Self-assembling tetranuclear complexes of a tridentate Schiff base

A tetranuclear KZn 3 complex consisting of three tridentate dibasic N 2 O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {...

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Bibliographic Details
Published in:Journal of coordination chemistry 2008-01, Vol.61 (1), p.85-91
Main Authors: Burlov, Anatolii S., Koshchienko, Yurii V., Lyssenko, Konstantin A., Vasilchenko, Igor S., Alexeev, Yurii E., Borodkina, Inna G., Antipin, Mikhail Yu, Garnovskii, Alexander D.
Format: Article
Language:English
Subjects:
Schiff base
Self-assembled crystal structure
Tetranuclear metallochelates
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Summary:A tetranuclear KZn 3 complex consisting of three tridentate dibasic N 2 O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {[ZnL] 3 OMe} − units are assembled by K...ON 2 contacts into layers. Mutual position of the KO 6 and {[ZnL] 3 OMe} − fragments of neighboring layers is temperature dependent.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970701732220