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Self-assembling tetranuclear complexes of a tridentate Schiff base
A tetranuclear KZn 3 complex consisting of three tridentate dibasic N 2 O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {...
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Published in: | Journal of coordination chemistry 2008-01, Vol.61 (1), p.85-91 |
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Main Authors: | , , , , , , , |
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cites | cdi_FETCH-LOGICAL-c412t-48a203d9af758dfea48ccbde4dcf5c2da83844ff477dc698b69e16b9a31c99303 |
container_end_page | 91 |
container_issue | 1 |
container_start_page | 85 |
container_title | Journal of coordination chemistry |
container_volume | 61 |
creator | Burlov, Anatolii S. Koshchienko, Yurii V. Lyssenko, Konstantin A. Vasilchenko, Igor S. Alexeev, Yurii E. Borodkina, Inna G. Antipin, Mikhail Yu Garnovskii, Alexander D. |
description | A tetranuclear KZn
3
complex consisting of three tridentate dibasic N
2
O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {[ZnL]
3
OMe}
−
units are assembled by K...ON
2
contacts into layers. Mutual position of the KO
6
and {[ZnL]
3
OMe}
−
fragments of neighboring layers is temperature dependent. |
doi_str_mv | 10.1080/00958970701732220 |
format | article |
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3
complex consisting of three tridentate dibasic N
2
O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {[ZnL]
3
OMe}
−
units are assembled by K...ON
2
contacts into layers. Mutual position of the KO
6
and {[ZnL]
3
OMe}
−
fragments of neighboring layers is temperature dependent.</description><identifier>ISSN: 0095-8972</identifier><identifier>EISSN: 1029-0389</identifier><identifier>DOI: 10.1080/00958970701732220</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><subject>Schiff base ; Self-assembled crystal structure ; Tetranuclear metallochelates</subject><ispartof>Journal of coordination chemistry, 2008-01, Vol.61 (1), p.85-91</ispartof><rights>Copyright Taylor & Francis Group, LLC 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-48a203d9af758dfea48ccbde4dcf5c2da83844ff477dc698b69e16b9a31c99303</citedby><cites>FETCH-LOGICAL-c412t-48a203d9af758dfea48ccbde4dcf5c2da83844ff477dc698b69e16b9a31c99303</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Burlov, Anatolii S.</creatorcontrib><creatorcontrib>Koshchienko, Yurii V.</creatorcontrib><creatorcontrib>Lyssenko, Konstantin A.</creatorcontrib><creatorcontrib>Vasilchenko, Igor S.</creatorcontrib><creatorcontrib>Alexeev, Yurii E.</creatorcontrib><creatorcontrib>Borodkina, Inna G.</creatorcontrib><creatorcontrib>Antipin, Mikhail Yu</creatorcontrib><creatorcontrib>Garnovskii, Alexander D.</creatorcontrib><title>Self-assembling tetranuclear complexes of a tridentate Schiff base</title><title>Journal of coordination chemistry</title><description>A tetranuclear KZn
3
complex consisting of three tridentate dibasic N
2
O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {[ZnL]
3
OMe}
−
units are assembled by K...ON
2
contacts into layers. Mutual position of the KO
6
and {[ZnL]
3
OMe}
−
fragments of neighboring layers is temperature dependent.</description><subject>Schiff base</subject><subject>Self-assembled crystal structure</subject><subject>Tetranuclear metallochelates</subject><issn>0095-8972</issn><issn>1029-0389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqF0MtKAzEUBuAgCtbqA7jLC4yeXNok4EaLNyi4qK6HM7noSGamJBHbt3dK3RV0dRbnfD-cn5BLBlcMNFwDmJk2ChQwJTjncEQmDLipQGhzTCa7fTUe8FNylvMnABOCqwm5W_kYKszZd01s-3dafEnYf9noMVE7dOvoNz7TIVCkJbXO9wWLpyv70YZAG8z-nJwEjNlf_M4peXu4f108VcuXx-fF7bKykvFSSY0chDMY1Ey74FFqaxvnpbNhZrlDLbSUIUilnJ0b3cyNZ_PGoGDWGAFiStg-16Yh5-RDvU5th2lbM6h3JdQHJYzmZm_aPgypw-8hRVcX3MYhhfFP2-Za_MXVv_xA1WVTxA9C83VL</recordid><startdate>20080101</startdate><enddate>20080101</enddate><creator>Burlov, Anatolii S.</creator><creator>Koshchienko, Yurii V.</creator><creator>Lyssenko, Konstantin A.</creator><creator>Vasilchenko, Igor S.</creator><creator>Alexeev, Yurii E.</creator><creator>Borodkina, Inna G.</creator><creator>Antipin, Mikhail Yu</creator><creator>Garnovskii, Alexander D.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080101</creationdate><title>Self-assembling tetranuclear complexes of a tridentate Schiff base</title><author>Burlov, Anatolii S. ; Koshchienko, Yurii V. ; Lyssenko, Konstantin A. ; Vasilchenko, Igor S. ; Alexeev, Yurii E. ; Borodkina, Inna G. ; Antipin, Mikhail Yu ; Garnovskii, Alexander D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-48a203d9af758dfea48ccbde4dcf5c2da83844ff477dc698b69e16b9a31c99303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Schiff base</topic><topic>Self-assembled crystal structure</topic><topic>Tetranuclear metallochelates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Burlov, Anatolii S.</creatorcontrib><creatorcontrib>Koshchienko, Yurii V.</creatorcontrib><creatorcontrib>Lyssenko, Konstantin A.</creatorcontrib><creatorcontrib>Vasilchenko, Igor S.</creatorcontrib><creatorcontrib>Alexeev, Yurii E.</creatorcontrib><creatorcontrib>Borodkina, Inna G.</creatorcontrib><creatorcontrib>Antipin, Mikhail Yu</creatorcontrib><creatorcontrib>Garnovskii, Alexander D.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burlov, Anatolii S.</au><au>Koshchienko, Yurii V.</au><au>Lyssenko, Konstantin A.</au><au>Vasilchenko, Igor S.</au><au>Alexeev, Yurii E.</au><au>Borodkina, Inna G.</au><au>Antipin, Mikhail Yu</au><au>Garnovskii, Alexander D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-assembling tetranuclear complexes of a tridentate Schiff base</atitle><jtitle>Journal of coordination chemistry</jtitle><date>2008-01-01</date><risdate>2008</risdate><volume>61</volume><issue>1</issue><spage>85</spage><epage>91</epage><pages>85-91</pages><issn>0095-8972</issn><eissn>1029-0389</eissn><abstract>A tetranuclear KZn
3
complex consisting of three tridentate dibasic N
2
O donor ligands (derived from mono-N-phenyl-substituted 5-nitro-o-phenylenediamine) and one methylato group has been synthesized. Single-crystal multi-temperature (100-350K) X-ray diffraction studies of the complex reveal that {[ZnL]
3
OMe}
−
units are assembled by K...ON
2
contacts into layers. Mutual position of the KO
6
and {[ZnL]
3
OMe}
−
fragments of neighboring layers is temperature dependent.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00958970701732220</doi><tpages>7</tpages></addata></record> |
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ispartof | Journal of coordination chemistry, 2008-01, Vol.61 (1), p.85-91 |
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language | eng |
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source | Taylor and Francis:Jisc Collections:Taylor and Francis Read and Publish Agreement 2024-2025:Science and Technology Collection (Reading list) |
subjects | Schiff base Self-assembled crystal structure Tetranuclear metallochelates |
title | Self-assembling tetranuclear complexes of a tridentate Schiff base |
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