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Multi-residue method for the determination of 450 pesticide residues in honey, fruit juice and wine by double-cartridge solid-phase extraction/gas chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry

A multi-residue method was developed for the determination of 450 pesticide residues in honey, fruit juice and wine using double-cartridge solid-phase extraction (SPE), gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-tandem mass spectrometry (LC-MS-MS). The method development...

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Published in:Food additives and contaminants 2006-08, Vol.23 (8), p.777-810
Main Authors: Pang, G.F, Fan, C.L, Liu, Y.M, Cao, Y.Z, Zhang, J.J, Fu, B.L, Li, X.M, Li, Z.Y, Wu, Y.P
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cited_by cdi_FETCH-LOGICAL-c455t-de573aac1e62867743c99f2149d4fbebb1d01c9878cffec0d0a6db9c2e4452b43
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container_title Food additives and contaminants
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creator Pang, G.F
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description A multi-residue method was developed for the determination of 450 pesticide residues in honey, fruit juice and wine using double-cartridge solid-phase extraction (SPE), gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-tandem mass spectrometry (LC-MS-MS). The method development was based on an appraisal of the characteristics of GC-MS and LC-MS-MS for 654 pesticides as well as the efficiency of extraction and purification from honey, fruit juice and wine. Samples were first diluted with water plus acetone, then extracted with portions of dichloromethane. The extracts were concentrated and cleaned up with graphitized carbon black and aminopropyl cartridges stacked in tandem. Pesticides were eluted with acetonitrile + toluene, and the eluates were concentrated. For 383 pesticides, the eluate was extracted with hexane twice and internal standard solution was added prior to GC-MS determination. For 67 pesticides, extraction was with methanol prior to LC-MS-MS determination. The limit of detection for the method was between 1.0 and 300 ng g-1 depending on each pesticide analyte. At the three fortification levels of 2.0-3000 ng g-1, the average recovery rates were between 59 and 123%, among which 413 pesticides (92% of the 450) had recovery rates of 70-120% and 35 pesticides (8% of the 450) had recovery rates of 59-70%. There were 437 pesticides (97% of the 450) with a relative standard deviation below 25%; there were 13 varieties (3% of the 450) between 25.0 and 30.4%.
doi_str_mv 10.1080/02652030600657997
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The method development was based on an appraisal of the characteristics of GC-MS and LC-MS-MS for 654 pesticides as well as the efficiency of extraction and purification from honey, fruit juice and wine. Samples were first diluted with water plus acetone, then extracted with portions of dichloromethane. The extracts were concentrated and cleaned up with graphitized carbon black and aminopropyl cartridges stacked in tandem. Pesticides were eluted with acetonitrile + toluene, and the eluates were concentrated. For 383 pesticides, the eluate was extracted with hexane twice and internal standard solution was added prior to GC-MS determination. For 67 pesticides, extraction was with methanol prior to LC-MS-MS determination. The limit of detection for the method was between 1.0 and 300 ng g-1 depending on each pesticide analyte. At the three fortification levels of 2.0-3000 ng g-1, the average recovery rates were between 59 and 123%, among which 413 pesticides (92% of the 450) had recovery rates of 70-120% and 35 pesticides (8% of the 450) had recovery rates of 59-70%. There were 437 pesticides (97% of the 450) with a relative standard deviation below 25%; there were 13 varieties (3% of the 450) between 25.0 and 30.4%.</abstract><cop>England</cop><pub>Taylor &amp; Francis Group</pub><pmid>16807205</pmid><doi>10.1080/02652030600657997</doi><tpages>34</tpages></addata></record>
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ispartof Food additives and contaminants, 2006-08, Vol.23 (8), p.777-810
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recordid cdi_informaworld_taylorfrancis_310_1080_02652030600657997
source Taylor and Francis:Jisc Collections:Taylor and Francis Read and Publish Agreement 2024-2025:Science and Technology Collection (Reading list)
subjects Beverages - analysis
capillary gas chromatography
Chromatography, Liquid - methods
food contamination
Food Contamination - analysis
Fruit
fruit juice
fruit juices
gas chromatography-mass spectrometry (GC-MS)
Gas Chromatography-Mass Spectrometry - methods
honey
Honey - analysis
liquid chromatography-tandem mass spectrometry (LC-MS-MS)
mass spectrometry
multiresidue analysis
Pesticide multi-residue analysis
pesticide residues
Pesticide Residues - analysis
Reproducibility of Results
solid phase extraction
Tandem Mass Spectrometry - methods
Vitaceae
wine
Wine - analysis
wines
title Multi-residue method for the determination of 450 pesticide residues in honey, fruit juice and wine by double-cartridge solid-phase extraction/gas chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry
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