Tribochemistry of Fluorinated Fluids Hydroxyl Groups on Steel and Aluminum Surfaces

This paper describes products of tribochemical reactions of Z-Dol 2500 and 1H,1H,2H,2H-tetra-fluorooctanol, produced on steel and aluminum surfaces. The fluorooctanol was used as a model compound to study the reactions of hydroxyl groups. Tribochemical reactions were initiated by friction in the ste...

Full description

Saved in:
Bibliographic Details
Published in:ASLE transactions 2006-04, Vol.49 (2), p.202-214
Main Authors: Przedlacki, Marcin, Kajdas, Czesław
Format: Article
Language:English
Subjects:
Applied sciences
Boundary Lubrication
Chemical reactions
Chemistry
Exact sciences and technology
Fluids
Fluorocarbons
Fourier Transform Infrared Spectroscopy
Friction
Friction, wear, lubrication
Machine components
Mechanical engineering. Machine design
Metals
Polyethers
Scientific imaging
Tribology
X-Ray Photoelectron Spectroscopy
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3
cites cdi_FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3
container_end_page 214
container_issue 2
container_start_page 202
container_title ASLE transactions
container_volume 49
creator Przedlacki, Marcin
Kajdas, Czesław
description This paper describes products of tribochemical reactions of Z-Dol 2500 and 1H,1H,2H,2H-tetra-fluorooctanol, produced on steel and aluminum surfaces. The fluorooctanol was used as a model compound to study the reactions of hydroxyl groups. Tribochemical reactions were initiated by friction in the steel/steel and steel/Al contacts, using an Optimol SRV (Schwingung Reibung Verschleiβ) reciprocating sliding tester. The products of these reactions, deposited in the wear scars on steel and Al discs, were studied using reflective FTIR spectrometry (microscopy and grazing angle) and X-Ray photoelectron spectroscopy (XPS). Under boundary lubrication conditions on metal surfaces, fluorinated compounds containing hydroxyl groups formed carboxylic and alkoxyl salts. FTIR spectra indicate that Fe and Al carboxylic salts occur mainly in bidentate configuration. Presented at the STLE Annual Meeting in Las Vegas, Nevada May 15-19, 2005 Review led by Tom Karis
doi_str_mv 10.1080/05698190500544676
format article
fullrecord <record><control><sourceid>proquest_infor</sourceid><recordid>TN_cdi_informaworld_taylorfrancis_310_1080_05698190500544676</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29217520</sourcerecordid><originalsourceid>FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3</originalsourceid><addsrcrecordid>eNqFkUlL7UAQRoP4wPEHuGsE3eXZ8wBuRBweCC6uD9w1PQUjnfS1O8Gbf28uVxEUdFW1OKeKr6qqjhD8i6CEZ5BxJZGCDEJGKRd8q9pFjIqaKPG4PfeQwhpDSHeqvVKeIUQMIbJbLR5ya5N7Cl1bhjyB1IDrOKbc9mYIft23voDbyee0miK4yWlcFpB6sBhCiMD0HlzEsWv7sQOLMTfGhXJQ_WlMLOHwve5X_6-vHi5v67v7m3-XF3e1YwQNtSWNs54zRom31iBplPGMCyuUm9MIy4MUniEvAiVKUakC5xYL6axspPdkvzrdzF3m9DKGMug5hAsxmj6ksWjCsZyPwn8FscJIMAxn8PgL-JzG3M8hNMaMcCnRGkIbyOVUSg6NXua2M3nSCOr1M_S3Z8zOyftgU5yJTTa9a8unKKTAWNKZO99wbd-k3JnXlKPXg5liyh8S-WmN-FX_ZulhNZA3SiOuhg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>225368810</pqid></control><display><type>article</type><title>Tribochemistry of Fluorinated Fluids Hydroxyl Groups on Steel and Aluminum Surfaces</title><source>Taylor and Francis Science and Technology Collection</source><creator>Przedlacki, Marcin ; Kajdas, Czesław</creator><creatorcontrib>Przedlacki, Marcin ; Kajdas, Czesław</creatorcontrib><description>This paper describes products of tribochemical reactions of Z-Dol 2500 and 1H,1H,2H,2H-tetra-fluorooctanol, produced on steel and aluminum surfaces. The fluorooctanol was used as a model compound to study the reactions of hydroxyl groups. Tribochemical reactions were initiated by friction in the steel/steel and steel/Al contacts, using an Optimol SRV (Schwingung Reibung Verschleiβ) reciprocating sliding tester. The products of these reactions, deposited in the wear scars on steel and Al discs, were studied using reflective FTIR spectrometry (microscopy and grazing angle) and X-Ray photoelectron spectroscopy (XPS). Under boundary lubrication conditions on metal surfaces, fluorinated compounds containing hydroxyl groups formed carboxylic and alkoxyl salts. FTIR spectra indicate that Fe and Al carboxylic salts occur mainly in bidentate configuration. Presented at the STLE Annual Meeting in Las Vegas, Nevada May 15-19, 2005 Review led by Tom Karis</description><identifier>ISSN: 1040-2004</identifier><identifier>ISSN: 0569-8197</identifier><identifier>EISSN: 1547-397X</identifier><identifier>DOI: 10.1080/05698190500544676</identifier><identifier>CODEN: TRTRE4</identifier><language>eng</language><publisher>Colchester: Taylor &amp; Francis Group</publisher><subject>Applied sciences ; Boundary Lubrication ; Chemical reactions ; Chemistry ; Exact sciences and technology ; Fluids ; Fluorocarbons ; Fourier Transform Infrared Spectroscopy ; Friction ; Friction, wear, lubrication ; Machine components ; Mechanical engineering. Machine design ; Metals ; Polyethers ; Scientific imaging ; Tribology ; X-Ray Photoelectron Spectroscopy</subject><ispartof>ASLE transactions, 2006-04, Vol.49 (2), p.202-214</ispartof><rights>Copyright Taylor &amp; Francis Group, LLC 2006</rights><rights>2006 INIST-CNRS</rights><rights>Copyright Society of Tribologists and Lubrication Engineers Apr-Jun 2006</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3</citedby><cites>FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17872284$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Przedlacki, Marcin</creatorcontrib><creatorcontrib>Kajdas, Czesław</creatorcontrib><title>Tribochemistry of Fluorinated Fluids Hydroxyl Groups on Steel and Aluminum Surfaces</title><title>ASLE transactions</title><description>This paper describes products of tribochemical reactions of Z-Dol 2500 and 1H,1H,2H,2H-tetra-fluorooctanol, produced on steel and aluminum surfaces. The fluorooctanol was used as a model compound to study the reactions of hydroxyl groups. Tribochemical reactions were initiated by friction in the steel/steel and steel/Al contacts, using an Optimol SRV (Schwingung Reibung Verschleiβ) reciprocating sliding tester. The products of these reactions, deposited in the wear scars on steel and Al discs, were studied using reflective FTIR spectrometry (microscopy and grazing angle) and X-Ray photoelectron spectroscopy (XPS). Under boundary lubrication conditions on metal surfaces, fluorinated compounds containing hydroxyl groups formed carboxylic and alkoxyl salts. FTIR spectra indicate that Fe and Al carboxylic salts occur mainly in bidentate configuration. Presented at the STLE Annual Meeting in Las Vegas, Nevada May 15-19, 2005 Review led by Tom Karis</description><subject>Applied sciences</subject><subject>Boundary Lubrication</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Fluids</subject><subject>Fluorocarbons</subject><subject>Fourier Transform Infrared Spectroscopy</subject><subject>Friction</subject><subject>Friction, wear, lubrication</subject><subject>Machine components</subject><subject>Mechanical engineering. Machine design</subject><subject>Metals</subject><subject>Polyethers</subject><subject>Scientific imaging</subject><subject>Tribology</subject><subject>X-Ray Photoelectron Spectroscopy</subject><issn>1040-2004</issn><issn>0569-8197</issn><issn>1547-397X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkUlL7UAQRoP4wPEHuGsE3eXZ8wBuRBweCC6uD9w1PQUjnfS1O8Gbf28uVxEUdFW1OKeKr6qqjhD8i6CEZ5BxJZGCDEJGKRd8q9pFjIqaKPG4PfeQwhpDSHeqvVKeIUQMIbJbLR5ya5N7Cl1bhjyB1IDrOKbc9mYIft23voDbyee0miK4yWlcFpB6sBhCiMD0HlzEsWv7sQOLMTfGhXJQ_WlMLOHwve5X_6-vHi5v67v7m3-XF3e1YwQNtSWNs54zRom31iBplPGMCyuUm9MIy4MUniEvAiVKUakC5xYL6axspPdkvzrdzF3m9DKGMug5hAsxmj6ksWjCsZyPwn8FscJIMAxn8PgL-JzG3M8hNMaMcCnRGkIbyOVUSg6NXua2M3nSCOr1M_S3Z8zOyftgU5yJTTa9a8unKKTAWNKZO99wbd-k3JnXlKPXg5liyh8S-WmN-FX_ZulhNZA3SiOuhg</recordid><startdate>20060401</startdate><enddate>20060401</enddate><creator>Przedlacki, Marcin</creator><creator>Kajdas, Czesław</creator><general>Taylor &amp; Francis Group</general><general>Taylor &amp; Francis</general><general>Taylor &amp; Francis Inc</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FR3</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>L7M</scope><scope>M2P</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope><scope>7QF</scope><scope>7SE</scope></search><sort><creationdate>20060401</creationdate><title>Tribochemistry of Fluorinated Fluids Hydroxyl Groups on Steel and Aluminum Surfaces</title><author>Przedlacki, Marcin ; Kajdas, Czesław</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Boundary Lubrication</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Fluids</topic><topic>Fluorocarbons</topic><topic>Fourier Transform Infrared Spectroscopy</topic><topic>Friction</topic><topic>Friction, wear, lubrication</topic><topic>Machine components</topic><topic>Mechanical engineering. Machine design</topic><topic>Metals</topic><topic>Polyethers</topic><topic>Scientific imaging</topic><topic>Tribology</topic><topic>X-Ray Photoelectron Spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Przedlacki, Marcin</creatorcontrib><creatorcontrib>Kajdas, Czesław</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>Engineering Research Database</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><collection>Aluminium Industry Abstracts</collection><collection>Corrosion Abstracts</collection><jtitle>ASLE transactions</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Przedlacki, Marcin</au><au>Kajdas, Czesław</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tribochemistry of Fluorinated Fluids Hydroxyl Groups on Steel and Aluminum Surfaces</atitle><jtitle>ASLE transactions</jtitle><date>2006-04-01</date><risdate>2006</risdate><volume>49</volume><issue>2</issue><spage>202</spage><epage>214</epage><pages>202-214</pages><issn>1040-2004</issn><issn>0569-8197</issn><eissn>1547-397X</eissn><coden>TRTRE4</coden><abstract>This paper describes products of tribochemical reactions of Z-Dol 2500 and 1H,1H,2H,2H-tetra-fluorooctanol, produced on steel and aluminum surfaces. The fluorooctanol was used as a model compound to study the reactions of hydroxyl groups. Tribochemical reactions were initiated by friction in the steel/steel and steel/Al contacts, using an Optimol SRV (Schwingung Reibung Verschleiβ) reciprocating sliding tester. The products of these reactions, deposited in the wear scars on steel and Al discs, were studied using reflective FTIR spectrometry (microscopy and grazing angle) and X-Ray photoelectron spectroscopy (XPS). Under boundary lubrication conditions on metal surfaces, fluorinated compounds containing hydroxyl groups formed carboxylic and alkoxyl salts. FTIR spectra indicate that Fe and Al carboxylic salts occur mainly in bidentate configuration. Presented at the STLE Annual Meeting in Las Vegas, Nevada May 15-19, 2005 Review led by Tom Karis</abstract><cop>Colchester</cop><pub>Taylor &amp; Francis Group</pub><doi>10.1080/05698190500544676</doi><tpages>13</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1040-2004
ispartof ASLE transactions, 2006-04, Vol.49 (2), p.202-214
issn 1040-2004
0569-8197
1547-397X
language eng
recordid cdi_informaworld_taylorfrancis_310_1080_05698190500544676
source Taylor and Francis Science and Technology Collection
subjects Applied sciences
Boundary Lubrication
Chemical reactions
Chemistry
Exact sciences and technology
Fluids
Fluorocarbons
Fourier Transform Infrared Spectroscopy
Friction
Friction, wear, lubrication
Machine components
Mechanical engineering. Machine design
Metals
Polyethers
Scientific imaging
Tribology
X-Ray Photoelectron Spectroscopy
title Tribochemistry of Fluorinated Fluids Hydroxyl Groups on Steel and Aluminum Surfaces
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T08%3A45%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_infor&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tribochemistry%20of%20Fluorinated%20Fluids%20Hydroxyl%20Groups%20on%20Steel%20and%20Aluminum%20Surfaces&rft.jtitle=ASLE%20transactions&rft.au=Przedlacki,%20Marcin&rft.date=2006-04-01&rft.volume=49&rft.issue=2&rft.spage=202&rft.epage=214&rft.pages=202-214&rft.issn=1040-2004&rft.eissn=1547-397X&rft.coden=TRTRE4&rft_id=info:doi/10.1080/05698190500544676&rft_dat=%3Cproquest_infor%3E29217520%3C/proquest_infor%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c531t-b3fcbd65543dbba18a9ad567b79c5697b6e87d51d7e4399489e66b278cb8f8dd3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=225368810&rft_id=info:pmid/&rfr_iscdi=true