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The Adsorption and Reaction of Decomposition Products of Zinc Di-Isopropyldiophosphate on Steel

Rates of adsorption and desorption, of di-isopropyldithiophosphoric acid and tetraisopropylthioperoxydiphosphate from hexade-cane on to steel, have been measured wing 14 C radiolabelled compounds. Concentration, temperature, and stirring dependence have been examined. The adsorption is surface contr...

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Bibliographic Details
Published in:ASLE transactions 1984-01, Vol.27 (3), p.252-258
Main Authors: Bovington, C. H., Dacre, B.
Format: Article
Language:English
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Summary:Rates of adsorption and desorption, of di-isopropyldithiophosphoric acid and tetraisopropylthioperoxydiphosphate from hexade-cane on to steel, have been measured wing 14 C radiolabelled compounds. Concentration, temperature, and stirring dependence have been examined. The adsorption is surface controlled and the kinetics can be represented by a Langmuir model. Correlation of rate data with antiwear properties is examined. Presented as an American Society of Lubrication Engineers paper at the ASLE/ASME Lubrication Conference in Hartford, Connecticut, October 18-20, 1983
ISSN:0569-8197
2375-1444
DOI:10.1080/05698198408981568