Aspects of Imido Phosphorus Chemistry

Phosphorus trichloride and phenyldichlorophosphine were reacted with two equivalents of benzophenone hydrazone and metallated stoichiometrically with nbutyllithium, to crystallize Li2(BuP(N 2 CPh 2 ) 2 ) and Li 2 (PhP(N 2 CPh 2 ) 2 ) respectively. An investigation into the synthesis of alternative m...

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2001-01, Vol.169 (1), p.27-30
Main Authors: Leedham, Angela P., Russell, Christopher A.
Format: Article
Language:English
Subjects:
imido
lithium
phosphorus
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Summary:Phosphorus trichloride and phenyldichlorophosphine were reacted with two equivalents of benzophenone hydrazone and metallated stoichiometrically with nbutyllithium, to crystallize Li2(BuP(N 2 CPh 2 ) 2 ) and Li 2 (PhP(N 2 CPh 2 ) 2 ) respectively. An investigation into the synthesis of alternative metal containing imidophosphorus complexes using similar methodology has produced complexes of ((EtZn)PhP(NPhOMe) 2 EtZn) 2 and PhP(NNCPh 2 ) 3 (PhHg) 3 Cl.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426500108546582