A Mild and Efficient Method for Oxidative Deprotection of Trimethylsilyl Ethers to the Corresponding Carbonyl Compounds Using [PhCH2NMe2Ph]2S2O8

Deprotection of trimethylsilyl ethers to the parent aldehydes and ketones in high yields has been carried out under mild conditions using N-benzyl N,N-dimethyl anilinium peroxodisulfate.

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2008-06, Vol.183 (6), p.1496-1500
Main Authors: Ghasemnejad-Bosra, Hassan, Tajbakhsh, Mahmood, Ramzanian-Lehmali, Farhad, Shabani-Mahali, Majid, Khalilzadeh, Mohammad A.
Format: Article
Language:English
Subjects:
Deprotection
N-benzyl N,N-dimethyl anilinium peroxodisulfate
oxidation
trimethylsilyl ethers
Online Access:Get full text
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Description
Summary:Deprotection of trimethylsilyl ethers to the parent aldehydes and ketones in high yields has been carried out under mild conditions using N-benzyl N,N-dimethyl anilinium peroxodisulfate.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426500701688214