Bisaryldithiophosphonic Acids: Synthesis and Their Reactions with Organyl Chlorosilanes, Germanes, Stannanes, and Plumbanes

A method of synthesizing arylbisdithiophosphonic acids was developed by the reaction of 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides with tri(ethylene glycol) and 1,4-butandiol in anhydrous benzene suspension under mild conditions. The arylbisdithiophosphonic acids thus obtained were transf...

Full description

Saved in:
Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2010-04, Vol.185 (4), p.732-742
Main Authors: Nizamov, Il'yas S., Gabdullina, Gulnara T., Nizamov, Ilnar D., Nikitin, Yevgeniy N., Al'metkina, Lyubov A., Cherkasov, Rafael A.
Format: Article
Language:English
Subjects:
1,3,2,4-dithiadiphosphetane-2,4-disulfides
Acids
Bisdithiophosphonic acids
Chemical industry
chlorogermanes
chloroplumbanes
chlorosilanes
chlorostannanes
glycols
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A method of synthesizing arylbisdithiophosphonic acids was developed by the reaction of 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides with tri(ethylene glycol) and 1,4-butandiol in anhydrous benzene suspension under mild conditions. The arylbisdithiophosphonic acids thus obtained were transformed into the corresponding diammonium salts. New bis(triorganylgermyl), stannyl and plumbyl, and cyclic diphenylsilyl and diphenylplumbyl derivatives of arylbisdithiophosphonic acids were prepared from the reactions of diammonium salts of the corresponding acids with triorganylchlorogermane, chlorostannane, chloroplumbane, diphenyldichlorosilane, and diphenyl dichloroplumbane.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426500902930142