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The Effect of Molecular Shape and Microphase Segregation on the Formation of Liquid Crystal Phases in Poly-Ols

In this article we examine the effect of molecular shape on the formation of thermotropic phases of alkyl-substituted poly-ols. The relationship between the cross-sectional area of the hydrophilic head group with respect to the that of the hydrophilic tails determines the type of mesophase formed. T...

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Published in:Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals Molecular crystals and liquid crystals, 2001-06, Vol.362 (1), p.23-44
Main Authors: West, Jonathan J., Bonsergent, Guenola, Mackenzie, Grahame, Ewing, David F., Goodby, John W., Benvegnu, Thierry, Plusquellec, Daniel, Bachir, Sabrina, Bault, Phillipe, Douillet, Olivier, Godé, Paul, Goethals, Gerard, Martin, Patrick, Villa, Pierre
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container_title Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals
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creator West, Jonathan J.
Bonsergent, Guenola
Mackenzie, Grahame
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Goodby, John W.
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Bachir, Sabrina
Bault, Phillipe
Douillet, Olivier
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Martin, Patrick
Villa, Pierre
description In this article we examine the effect of molecular shape on the formation of thermotropic phases of alkyl-substituted poly-ols. The relationship between the cross-sectional area of the hydrophilic head group with respect to the that of the hydrophilic tails determines the type of mesophase formed. The results obtained are similar to those found for the formation of lyotropic phases.
doi_str_mv 10.1080/10587250108025758
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ispartof Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 2001-06, Vol.362 (1), p.23-44
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source Taylor and Francis Science and Technology Collection
subjects Condensed matter: structure, mechanical and thermal properties
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Experimental determinations of smectic, nematic, cholesteric, and other structures
Liquid crystals
Physics
Specific phase transitions
Structure of solids and liquids
crystallography
Transitions in liquid crystals
title The Effect of Molecular Shape and Microphase Segregation on the Formation of Liquid Crystal Phases in Poly-Ols
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