Polymeric, H-Bonded, and Chelatable Phenoxyl and Nitroxide Radicals

Various examples are described of a multi-strategy approach to improvement of multispin exchange design. For example, H-bonded benzimidazole 4-t-butylnitroxide shows apparent simple planar 2D-type interaction, with a Weiss constant of Θ = −4.24 K and an intraplane exchange interaction of J = −1.60 K...

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Bibliographic Details
Published in:Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals Molecular crystals and liquid crystals, 1999-09, Vol.334 (1), p.285-294
Main Authors: Lahti, Paul M., Esat, Burak, Ferrer, Jacqueline R., Liu, Yanbing, Marby, Kenneth A., Xie, Chunping, George, Clifford, Antorrena, Guillermo, Palacio, Fernando
Format: Article
Language:English
Subjects:
hydrogen-bonding
magnetism
nitroxide
phenoxyl
polyradical
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Summary:Various examples are described of a multi-strategy approach to improvement of multispin exchange design. For example, H-bonded benzimidazole 4-t-butylnitroxide shows apparent simple planar 2D-type interaction, with a Weiss constant of Θ = −4.24 K and an intraplane exchange interaction of J = −1.60 K.
ISSN:1058-725X
DOI:10.1080/10587259908023326