Preparation of Non-Substituted Metal Phthalocyanines at Low Temperature Using Activated Rieke Zinc and Magnesium

Synthesis of non-substituted metal phthalocyaninates starting from phthalonitrile in various alcohols in presence of chemically activated Rieke zinc and magnesium in three forms (ordinary magnesium turnings, activated Rieke magnesium and complex Mg(anthracene) · 3THF) at low temperatures (20-50°C) i...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry metal-organic, and nano-metal chemistry, 2005-12, Vol.35 (10), p.755-760
Main Authors: Kharisov, B. I., Garza-Rodríguez, L. A., Leija Gutiérrez, H. M., Ortiz Méndez, U., García Caballero, R., Tsivadze, A. Yu
Format: Article
Language:English
Subjects:
Rieke metals
synthesis at low temperature
zinc and magnesium phthalocyaninate
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Summary:Synthesis of non-substituted metal phthalocyaninates starting from phthalonitrile in various alcohols in presence of chemically activated Rieke zinc and magnesium in three forms (ordinary magnesium turnings, activated Rieke magnesium and complex Mg(anthracene) · 3THF) at low temperatures (20-50°C) is described. It is shown that the presence of active elemental metal causes a rapid PcM formation in low-weight alcohols.
ISSN:1553-3174
1553-3182
DOI:10.1080/15533170500360248