Reduction of oxygenated organosulfur compounds

A comprehensive review on deoxygenation of sulfoxides to thioethers and reductive coupling of sulfonyl, sulfinyl and sulfenyl halides, sulfinates and thiosulfonates to their corresponding disulfides are discussed with different reagents and catalysts. The reported mechanisms for these transformation...

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Bibliographic Details
Published in:Journal of sulfur chemistry 2008-02, Vol.29 (1), p.53-97
Main Authors: Firouzabadi, Habib, Jamalian, Arezu
Format: Article
Language:English
Subjects:
deoxygenation
disulfides
oxidative coupling
reduction
reductive coupling
sulfenyl halides
sulfides
sulfinyl halides
sulfonic acids
sulfonyl derivatives
sulfonyl halides
sulfoxides
thioethers
thiosulfonates
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Summary:A comprehensive review on deoxygenation of sulfoxides to thioethers and reductive coupling of sulfonyl, sulfinyl and sulfenyl halides, sulfinates and thiosulfonates to their corresponding disulfides are discussed with different reagents and catalysts. The reported mechanisms for these transformations are also addressed.
ISSN:1741-5993
1741-6000
DOI:10.1080/17415990701684776