BROMODECARBONYLATION AND BROMODECARBOXYLATION OF ELECTRON-RICH BENZALDEHYDES AND BENZOIC ACIDS WITH OXONE® AND SODIUM BROMIDE

Benzaldehydes and benzoic acids bearing ortho- and para-electron donating substituents having unshared electron-pair have undergone bromodecarbonylation or bromodecarboxylation on treatment with sodium bromide in the presence of Oxone® in aqueous methanol.

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Bibliographic Details
Published in:Synthetic communications 2002-01, Vol.32 (15), p.2275-2286
Main Authors: Koo, Bon-Suk, Kim, Eun-Hoo, Lee, Kee-Jung
Format: Article
Language:English
Subjects:
Benzoic acids
Bromodecarboxylation
Bromodercarbonylation
Electron-rich benzaldehydes
Oxone
Sodium bromide
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Description
Summary:Benzaldehydes and benzoic acids bearing ortho- and para-electron donating substituents having unshared electron-pair have undergone bromodecarbonylation or bromodecarboxylation on treatment with sodium bromide in the presence of Oxone® in aqueous methanol.
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-120005997