Zn(II) and Pd(II) Complexes of Thiosemicarbazone-S-alkyl Esters Derived from 2/3-Formylpyridine

Representative S-methyl/ethyl-4-H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl 2 ], [Pd(L)Cl 2 ], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1 H NMR spectra. The multidentate S-alkyl thi...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic and metal-organic chemistry 2004-04, Vol.34 (4), p.653-665
Main Authors: Kızılcıklı, İrfan, Ülküseven, Bahri, Daşdemir, Yasemin, Akkurt, Barbaros
Format: Article
Language:English
Subjects:
Polydentate thiosemicarbazones
Zn(II) and Pd(II) complexes
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Summary:Representative S-methyl/ethyl-4-H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl 2 ], [Pd(L)Cl 2 ], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1 H NMR spectra. The multidentate S-alkyl thiosemicarbazones coordinate as mono-, bi-, or tridentate ligands depending on the types of the alkyl moiety and metal ion.
ISSN:0094-5714
1532-2440
DOI:10.1081/SIM-120035948