Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile

Data on the controlled synthesis of polyacrylonitrile and acrylonitrile copolymers with other (meth)acrylic and vinyl monomers upon radical initiation and metal complex catalysis are analyzed. Primary attention is given to the use of metal complexes for the synthesis of acrylonitrile-based (co)polym...

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Bibliographic Details
Published in:Russian chemical reviews 2015-01, Vol.84 (7), p.712-736
Main Authors: Grishin, D F, Grishin, I D
Format: Article
Language:English
Subjects:
Acrylonitriles
Arrays
Coordination compounds
Copolymers
Macromolecules
Polymerization
Radicals
Synthesis
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Summary:Data on the controlled synthesis of polyacrylonitrile and acrylonitrile copolymers with other (meth)acrylic and vinyl monomers upon radical initiation and metal complex catalysis are analyzed. Primary attention is given to the use of metal complexes for the synthesis of acrylonitrile-based (co)polymers with defined molecular weight and polydispersity in living mode by atom transfer radical polymerization. The prospects for using known methods of controlled synthesis of macromolecules for the preparation of acrylonitrile homo- and copolymers as carbon fibre precursors are estimated. The major array of published data analyzed in the review refers to the last decade. The bibliography includes 175 references.
ISSN:0036-021X
1468-4837
DOI:10.1070/RCR4476