No evidence for room temperature ferromagnetism in the high temperature metal-organic material: Ni2TCNQ

The search for ferromagnetic organic-based compounds has been a particular challenge to both chemists and physicists over the past few decades. The synthesis of the Ni2A, where A is an organic acceptor; tetracyanoethene (TCNE), 3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) or 7,7,8,8-tetracyanoquino...

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Bibliographic Details
Published in:Journal of physics. Condensed matter 2021-02, Vol.33 (6), p.065801-065801
Main Authors: Berlie, Adam, Terry, Ian, Szablewski, Marek, Quinn, Kimberly
Format: Article
Language:English
Subjects:
magnetisation
muon spin spectroscopy
organic magnet
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Summary:The search for ferromagnetic organic-based compounds has been a particular challenge to both chemists and physicists over the past few decades. The synthesis of the Ni2A, where A is an organic acceptor; tetracyanoethene (TCNE), 3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) or 7,7,8,8-tetracyanoquinodimethane (TCNQ) (Jain et al 2007 Nature 445 291), was reported to be a great advancement with claims that the ferromagnetism persisted to well above room temperature. There were, however some substantial flaws in the methodology associated with the synthesis and physical characterisation. Our work solely studies the Ni2TCNQ compound where we find no evidence for the existence of inherent ferromagnetism within the material that was reported in the original paper. Instead, we find that the magnetism is due to superparamagnetic nickel nanoparticles embedded in an amorphous matrix. It is hoped that our work will also show that one must be careful when using Ni(COD)2 as a precursor in the synthesis of magnetic materials and that the usefulness of the reported synthetic method is extremely limited.
ISSN:0953-8984
1361-648X
DOI:10.1088/1361-648X/abb545