Zeolitic Imidazolate Framework-8 Membrane for H2/CO2 Separation: Experimental and Modeling

In this work, ZIF-8 membrane synthesized through solvent evaporation secondary seeded growth was tested for single gas permeation and binary gases separation of H2 and CO2. Subsequently, a modified mathematical modeling combining the effects of membrane and support layers was applied to represent th...

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Bibliographic Details
Published in:IOP conference series. Materials Science and Engineering 2018-03, Vol.318 (1)
Main Authors: Lai, L S, Yeong, Y F, Lau, K K, Azmi, M S, Chew, T L
Format: Article
Language:English
Subjects:
Carbon dioxide
Gas permeation
Gas transport
Gases
Membranes
Metal-organic frameworks
Penetration
Selectivity
Separation
Transport properties
Zeolites
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Summary:In this work, ZIF-8 membrane synthesized through solvent evaporation secondary seeded growth was tested for single gas permeation and binary gases separation of H2 and CO2. Subsequently, a modified mathematical modeling combining the effects of membrane and support layers was applied to represent the gas transport properties of ZIF-8 membrane. Results showed that, the membrane has exhibited H2/CO2 ideal selectivity of 5.83 and separation factor of 3.28 at 100 kPa and 303 K. Besides, the experimental results were fitted well with the simulated results by demonstrating means absolute error (MAE) values ranged from 1.13 % to 3.88 % for single gas permeation and 10.81 % to 21.22 % for binary gases separation. Based on the simulated data, most of the H2 and CO2 gas molecules have transported through the molecular pores of membrane layer, which was up to 70 %. Thus, the gas transport of the gases is mainly dominated by adsorption and diffusion across the membrane.
ISSN:1757-8981
1757-899X
DOI:10.1088/1757-899X/318/1/012002