Optimization of ESC Performance for Co-Electrolysis Operation

• Published in: ECS transactions 2017-05, Vol.78 (1), p.3025-3037
• Main Authors: Trofimenko, Nikolai, Kusnezoff, Michails, Michaelis, Alexander
• Format: Article
• Language: English
• ISSN: 1938-5862; 1938-6737; 1938-6737; 1938-5862
• DOI: 10.1149/07801.3025ecst

Production of synthetic hydrocarbon fuels from co-electrolysis of steam/CO2 mixtures using renewable energy has been already presented as a promising solution to diminish environmental problems. The possibility to recycle CO2 into chemicals and value-added fuels helps to reduce the accumulation of atmospheric CO2 and realize the carbon neutral cycling of fuels. While the co-electrolysis is more complicated than steam electrolysis, the electrochemical performance of electrolyte supported cell with LSMM'/ScSZ and Ni/GDC electrodes were investigated over a wide range of operating conditions (SOEC as well as SOFC), varying the ratio of H2O:H2 and CO2:CO, the operating temperature (750-850°C) and current. The modified G3´´ cell with optimized fuel and air electrodes was successfully tested for ~2400 hours at 803°C under co-electrolysis conditions (H2/H2O/CO2/CO mixture as fuel, j = -400 mA/cm2). The calculated linear power degradation rate over all durability test (~2400 h) is about 0.4%/1,000 h.