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Considering Photon Scattering and Harmonics for Synchrotron X-ray Radiographic Imaging of Polymer Electrolyte Membrane Fuel Cells

We predicted the attenuated, undesired secondary scattered, and undesired harmonic components of measured X-ray intensities from synchrotron X-ray radiographic visualizations of liquid water in an operating polymer electrolyte membrane (PEM) fuel cell. The undesired secondary scattered component of...

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Bibliographic Details
Published in:Journal of the Electrochemical Society 2017-01, Vol.164 (11), p.E3215-E3224
Main Authors: Ge, Nan, George, Michael G., Lee, Jongmin, Muirhead, Daniel, Chevalier, Stéphane, Banerjee, Rupak, Liu, Hang, Wysokinski, Tomasz W., Belev, George, Webb, M. Adam, Zhu, Ning, Bazylak, Aimy
Format: Article
Language:English
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Summary:We predicted the attenuated, undesired secondary scattered, and undesired harmonic components of measured X-ray intensities from synchrotron X-ray radiographic visualizations of liquid water in an operating polymer electrolyte membrane (PEM) fuel cell. The undesired secondary scattered component of the measured intensity increased as a function of the liquid water thickness (traversed by the X-ray beam). This increase in the secondary scattered component led to a decrease in the calibrated attenuation coefficient for liquid water, decreasing the accuracy of water quantification. We recommend calibrating the attenuated coefficient with a range of water thicknesses defined by the maximum expected water thickness present in the PEM fuel cell. The undesired harmonic component of the measured intensity also increased as a function of liquid water thickness, which led to a decrease in the accuracy of the measured liquid water thickness.
ISSN:0013-4651
1945-7111
DOI:10.1149/2.0231711jes