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Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3
Changes in ferroelectric and structural antiphase domain structure by the partial substitution of nonmagnetic Ti 4+ ions at the Mn site were investigated carefully by electron diffraction, dark-field imaging, and high-resolution lattice imaging experiments. The ferroelectric and structural antiphase...
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Published in: | Jpn J Appl Phys 2012-09, Vol.51 (9), p.09LE09-09LE09-4 |
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container_issue | 9 |
container_start_page | 09LE09 |
container_title | Jpn J Appl Phys |
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creator | Kobayashi, Keisuke Koyama, Tsukasa Kamo, Hideki Togawa, Yoshihiko Horibe, Yoichi Cheong, Sang Wook Mori, Shigeo |
description | Changes in ferroelectric and structural antiphase domain structure by the partial substitution of nonmagnetic Ti 4+ ions at the Mn site were investigated carefully by electron diffraction, dark-field imaging, and high-resolution lattice imaging experiments. The ferroelectric and structural antiphase domains are revealed to be mutually interlocked in YMnO 3 and, on the other hand, when $x$ was increased up to $x\sim 0.30$ in YMn 1-x Ti x O 3 , the ferroelectric domains disappeared and the size of the structural antiphase domains decreased to approximately 10 nm at $x\sim 0.30$. High-resolution lattice images clearly demonstrate the coexisting state of nanodomains characterized by the modulated structure due to the structural trimerization and the nonmodulated structures. Our experimental results suggest that a partial substitution of Ti 4+ ions suppressed the ferroelectric displacement along the [001] direction and the correlation length of the Mn 3+ trimerization decreased. |
doi_str_mv | 10.1143/JJAP.51.09LE09 |
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The ferroelectric and structural antiphase domains are revealed to be mutually interlocked in YMnO 3 and, on the other hand, when $x$ was increased up to $x\sim 0.30$ in YMn 1-x Ti x O 3 , the ferroelectric domains disappeared and the size of the structural antiphase domains decreased to approximately 10 nm at $x\sim 0.30$. High-resolution lattice images clearly demonstrate the coexisting state of nanodomains characterized by the modulated structure due to the structural trimerization and the nonmodulated structures. Our experimental results suggest that a partial substitution of Ti 4+ ions suppressed the ferroelectric displacement along the [001] direction and the correlation length of the Mn 3+ trimerization decreased.</description><identifier>ISSN: 0021-4922</identifier><identifier>EISSN: 1347-4065</identifier><identifier>DOI: 10.1143/JJAP.51.09LE09</identifier><language>eng</language><publisher>The Japan Society of Applied Physics</publisher><ispartof>Jpn J Appl Phys, 2012-09, Vol.51 (9), p.09LE09-09LE09-4</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kobayashi, Keisuke</creatorcontrib><creatorcontrib>Koyama, Tsukasa</creatorcontrib><creatorcontrib>Kamo, Hideki</creatorcontrib><creatorcontrib>Togawa, Yoshihiko</creatorcontrib><creatorcontrib>Horibe, Yoichi</creatorcontrib><creatorcontrib>Cheong, Sang Wook</creatorcontrib><creatorcontrib>Mori, Shigeo</creatorcontrib><title>Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3</title><title>Jpn J Appl Phys</title><description>Changes in ferroelectric and structural antiphase domain structure by the partial substitution of nonmagnetic Ti 4+ ions at the Mn site were investigated carefully by electron diffraction, dark-field imaging, and high-resolution lattice imaging experiments. The ferroelectric and structural antiphase domains are revealed to be mutually interlocked in YMnO 3 and, on the other hand, when $x$ was increased up to $x\sim 0.30$ in YMn 1-x Ti x O 3 , the ferroelectric domains disappeared and the size of the structural antiphase domains decreased to approximately 10 nm at $x\sim 0.30$. High-resolution lattice images clearly demonstrate the coexisting state of nanodomains characterized by the modulated structure due to the structural trimerization and the nonmodulated structures. Our experimental results suggest that a partial substitution of Ti 4+ ions suppressed the ferroelectric displacement along the [001] direction and the correlation length of the Mn 3+ trimerization decreased.</description><issn>0021-4922</issn><issn>1347-4065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNotkM1PgzAchhujiTi9eu7ZBOyvH5QeycZ0C2YmzoMnUkrRKiuksIP_vSzz9ObJmzyHB6F7IAkAZ4_bbf6aCEiIKguiLlAEjMuYk1RcoogQCjFXlF6jm3H8njEVHCK0X_WD85-4aFtrJtx7vPGTDV1vfmyD1zaE3nbzE5zB2jf4bQpHMx2D7nDuJzd86dHiVX_Qzo_Yefzx4nfsFl21uhvt3f8u0Pu62C-f43L3tFnmZeyAkimWVDbSCFBEUA4Z1a1KM6VZxkRmjSJMkhlabowhtRKtzUAYaWRWpzVo3rAFejh73aCHagjuoMNvBaQ69ahOPSoB1bkH-wOSDlKm</recordid><startdate>20120925</startdate><enddate>20120925</enddate><creator>Kobayashi, Keisuke</creator><creator>Koyama, Tsukasa</creator><creator>Kamo, Hideki</creator><creator>Togawa, Yoshihiko</creator><creator>Horibe, Yoichi</creator><creator>Cheong, Sang Wook</creator><creator>Mori, Shigeo</creator><general>The Japan Society of Applied Physics</general><scope/></search><sort><creationdate>20120925</creationdate><title>Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3</title><author>Kobayashi, Keisuke ; Koyama, Tsukasa ; Kamo, Hideki ; Togawa, Yoshihiko ; Horibe, Yoichi ; Cheong, Sang Wook ; Mori, Shigeo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i120t-727d7c5190524182af9689a38358ec90370a38f4ccc0b95fe815c7c78b6b1a4d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kobayashi, Keisuke</creatorcontrib><creatorcontrib>Koyama, Tsukasa</creatorcontrib><creatorcontrib>Kamo, Hideki</creatorcontrib><creatorcontrib>Togawa, Yoshihiko</creatorcontrib><creatorcontrib>Horibe, Yoichi</creatorcontrib><creatorcontrib>Cheong, Sang Wook</creatorcontrib><creatorcontrib>Mori, Shigeo</creatorcontrib><jtitle>Jpn J Appl Phys</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kobayashi, Keisuke</au><au>Koyama, Tsukasa</au><au>Kamo, Hideki</au><au>Togawa, Yoshihiko</au><au>Horibe, Yoichi</au><au>Cheong, Sang Wook</au><au>Mori, Shigeo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3</atitle><jtitle>Jpn J Appl Phys</jtitle><date>2012-09-25</date><risdate>2012</risdate><volume>51</volume><issue>9</issue><spage>09LE09</spage><epage>09LE09-4</epage><pages>09LE09-09LE09-4</pages><issn>0021-4922</issn><eissn>1347-4065</eissn><abstract>Changes in ferroelectric and structural antiphase domain structure by the partial substitution of nonmagnetic Ti 4+ ions at the Mn site were investigated carefully by electron diffraction, dark-field imaging, and high-resolution lattice imaging experiments. The ferroelectric and structural antiphase domains are revealed to be mutually interlocked in YMnO 3 and, on the other hand, when $x$ was increased up to $x\sim 0.30$ in YMn 1-x Ti x O 3 , the ferroelectric domains disappeared and the size of the structural antiphase domains decreased to approximately 10 nm at $x\sim 0.30$. High-resolution lattice images clearly demonstrate the coexisting state of nanodomains characterized by the modulated structure due to the structural trimerization and the nonmodulated structures. Our experimental results suggest that a partial substitution of Ti 4+ ions suppressed the ferroelectric displacement along the [001] direction and the correlation length of the Mn 3+ trimerization decreased.</abstract><pub>The Japan Society of Applied Physics</pub><doi>10.1143/JJAP.51.09LE09</doi></addata></record> |
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title | Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3 |
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