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Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3

Changes in ferroelectric and structural antiphase domain structure by the partial substitution of nonmagnetic Ti 4+ ions at the Mn site were investigated carefully by electron diffraction, dark-field imaging, and high-resolution lattice imaging experiments. The ferroelectric and structural antiphase...

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Published in:Jpn J Appl Phys 2012-09, Vol.51 (9), p.09LE09-09LE09-4
Main Authors: Kobayashi, Keisuke, Koyama, Tsukasa, Kamo, Hideki, Togawa, Yoshihiko, Horibe, Yoichi, Cheong, Sang Wook, Mori, Shigeo
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container_issue 9
container_start_page 09LE09
container_title Jpn J Appl Phys
container_volume 51
creator Kobayashi, Keisuke
Koyama, Tsukasa
Kamo, Hideki
Togawa, Yoshihiko
Horibe, Yoichi
Cheong, Sang Wook
Mori, Shigeo
description Changes in ferroelectric and structural antiphase domain structure by the partial substitution of nonmagnetic Ti 4+ ions at the Mn site were investigated carefully by electron diffraction, dark-field imaging, and high-resolution lattice imaging experiments. The ferroelectric and structural antiphase domains are revealed to be mutually interlocked in YMnO 3 and, on the other hand, when $x$ was increased up to $x\sim 0.30$ in YMn 1-x Ti x O 3 , the ferroelectric domains disappeared and the size of the structural antiphase domains decreased to approximately 10 nm at $x\sim 0.30$. High-resolution lattice images clearly demonstrate the coexisting state of nanodomains characterized by the modulated structure due to the structural trimerization and the nonmodulated structures. Our experimental results suggest that a partial substitution of Ti 4+ ions suppressed the ferroelectric displacement along the [001] direction and the correlation length of the Mn 3+ trimerization decreased.
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title Doping Effect on Interlocked Ferroelectric and Structural Antiphase Domains in YMnO3
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