Field-Induced Metamagnetic Transition in the FeIII−MnIII Bimetallic Chain Built by a New Cyanide-Bearing FeIII Precursor

The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]·MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a fi...

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Bibliographic Details
Published in:Inorganic chemistry 2007-12, Vol.46 (25), p.10461-10463
Main Authors: Kim, Jae Il, Yoo, Houng Sik, Koh, Eui Kwan, Hong, Chang Seop
Format: Article
Language:eng ; jpn
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Summary:The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]·MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic702001q