Reactions of Bis(pentafluorophenyl)borane with Cp2Ta(CH2)CH3

Reactions of Schrock's methyl methylene complex Cp2Ta(CH2)CH3 with HB(C6F5)2 are described. Products arising from attack of the borane at the methylene ligand are isolated; the course of the reaction is dependent on the conditions employed and the equivalency of borane used.

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Bibliographic Details
Published in:Organometallics 1999-04, Vol.18 (9), p.1575-1577
Main Authors: Cook, Kevin S, Piers, Warren E, Rettig, Steven J
Format: Article
Language:English
Online Access:Get full text
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Summary:Reactions of Schrock's methyl methylene complex Cp2Ta(CH2)CH3 with HB(C6F5)2 are described. Products arising from attack of the borane at the methylene ligand are isolated; the course of the reaction is dependent on the conditions employed and the equivalency of borane used.
ISSN:0276-7333
1520-6041
DOI:10.1021/om9900418