Selenidobis(dithiolene)metal(IV) Complexes (Metal M = Mo, W) Potentially Related to the Nicotinic Acid Hydroxylase Reaction Center: Redox Aspects in Electrochemistry and Oxygen Atom Transfer from Me3NO to MIV Centers

Selenidobis(dithiolene)molybdenum(IV) and -tungsten(IV) complexes were synthesized and characterized by several methods including X-ray crystallographic analysis. The five-coordinate MVSe species were accessed by one-electron oxidation of the MIVSe complexes. MVISe complexes were suggested to be...

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Published in:Inorganic chemistry 2008-09, Vol.47 (17), p.7465-7467
Main Authors: Tano, Hiroyuki, Tajima, Reiko, Miyake, Hiroyuki, Itoh, Shinobu, Sugimoto, Hideki
Format: Article
Language:English
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Summary:Selenidobis(dithiolene)molybdenum(IV) and -tungsten(IV) complexes were synthesized and characterized by several methods including X-ray crystallographic analysis. The five-coordinate MVSe species were accessed by one-electron oxidation of the MIVSe complexes. MVISe complexes were suggested to be formed as an intermediate in oxygen atom transfer from Me3NO to the MIVSe centers.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic8009942