A Convergent Synthesis of (Z)-13-Octadecen-1-yl Acetate, the Pheromone Mimic of the Rice Leaf Folder Moth and Its Biological Activity Test

(Z)-13-Octadecen-1-yl acetate, the pheromone mimic of the Rice Leaf Folder Moth, Cnaphalocrosis medinalis, was synthesized from 1,13-tridecanediol in three steps. Monoacetylation of 1,13-tridecanediol followed by PCC oxidation gave 13-acetoxytridecan-1-al. Wittig olefination of the 13-acetoxytrideca...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 1985, Vol.6 (4), p.228-230
Main Authors: Kang Suk-Ku, Moon Byoung-Ho, Lee Jeang-Oon, Goh Hyun-Gwan
Format: Article
Language:Korean
Online Access:Get full text
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Summary:(Z)-13-Octadecen-1-yl acetate, the pheromone mimic of the Rice Leaf Folder Moth, Cnaphalocrosis medinalis, was synthesized from 1,13-tridecanediol in three steps. Monoacetylation of 1,13-tridecanediol followed by PCC oxidation gave 13-acetoxytridecan-1-al. Wittig olefination of the 13-acetoxytridecan-1-al with pentylidenetriphenylphosphonium ylide afforded (Z)-13-octadecen-1-yl acetate, the pheromone mimic of the Rice Leaf Folder.
ISSN:0253-2964
1229-5949