Carbonylation of (Dichloromethyl)benzene Catalyzed by Cobalt Carbonyl and Iron Carbonyl under Phase Transfer Catalysis

Treatment of (dichloromethyl)benzenes with CO (1 atm) in the presence of catalytic amount of $Co_2(CO)_8,\;Fe(CO)_5$ and BTEAC under two phase systems with NaOH(_{aq}) and $PhCH_3$ containing small amount of alcohol for 20 hours at 80$^{\circ}$C gives phenylacetic acids in moderate yields.

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 1993, Vol.14 (5), p.618-620
Main Authors: Sang Chul Shiim, Chil Hoon Doh, Dong Yub Lee, Jae Goo Shim, Young Zoo Youn, Woo Hyung Park, Li Hong Jiang, Ju Hee Kim
Format: Article
Language:Korean
Online Access:Get full text
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Summary:Treatment of (dichloromethyl)benzenes with CO (1 atm) in the presence of catalytic amount of $Co_2(CO)_8,\;Fe(CO)_5$ and BTEAC under two phase systems with NaOH(_{aq}) and $PhCH_3$ containing small amount of alcohol for 20 hours at 80$^{\circ}$C gives phenylacetic acids in moderate yields.
ISSN:0253-2964
1229-5949