Nonequilibrium Distribution Function Theory of Many-Particle Effects in the Reversible Reactions of the Type A+B ↔ C+B

We study the relaxation kinetics of reversible reactions of the type A + B $^\leftarrow_\rightarrow$ C + B by applying the manyparticle kernel theory, which we have developed to investigate many particle effects on general diffusioninfluenced reactions. It is shown that for the target model, where A...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2005, Vol.26 (12), p.1986-1990
Main Authors: Lee, Jin-Uk, Uhm, Je-Sik, Lee, Woo-Jin, Lee, Sang-Youb, Sung, Jae-Young
Format: Article
Language:Korean
Online Access:Get full text
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Summary:We study the relaxation kinetics of reversible reactions of the type A + B $^\leftarrow_\rightarrow$ C + B by applying the manyparticle kernel theory, which we have developed to investigate many particle effects on general diffusioninfluenced reactions. It is shown that for the target model, where A and C molecules are immobile and their interconversion is induced by the encounter with the B molecules that are present in much excess, the manyparticle kernel theory gives a result that coincides with the known exact result.
ISSN:0253-2964
1229-5949