Reaction of Ph2C(X)(CO2H) (X = OH, NH2) with [VO(OR)3] (R = Et, nPr): structure, magnetic susceptibility and ROP capability

Reaction of [VO(OR)3] (R = Et, nPr) with 2,2’-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(mu-OR)[Ph2C(NH2)(CO2)]}2, whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V8(O)4M(OR)8[Ph2C(OH)(CO2)]12} (M =

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Bibliographic Details
Main Authors: Mollie A Glenister, Josef Frese, Mark Elsegood, Angelos B Canaj, Euan K Brechin, Carl Redshaw
Format: Article
Language:English
Subjects:
Inorganic & Nuclear Chemistry
Inorganic chemistry
Other chemical sciences
Theoretical and computational chemistry
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Summary:Reaction of [VO(OR)3] (R = Et, nPr) with 2,2’-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(mu-OR)[Ph2C(NH2)(CO2)]}2, whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V8(O)4M(OR)8[Ph2C(OH)(CO2)]12} (M =