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Alchemists' Gold, Hg2.86 Asf6; An X-Ray Crystallographic Study of A Novel Disordered Mercury Compound Containing Metallically Bonded Infinite Cations
The compound Hg 2.86 AsF 6 belongs to the tetragonal space group I4 1 /amd with lattice parameters a = 7.538(4) Å, c = 12.339(5) Å, and Z = 4. The structure was refined using 109 symmetry independent reflections by full matrix least-squares refinement to a final R value of 0.079. The structure may b...
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| Published in: | Canadian journal of chemistry 1974-03, Vol.52 (5), p.791-793 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | eng ; jpn |
| Online Access: | Get full text |
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| container_end_page | 793 |
| container_issue | 5 |
| container_start_page | 791 |
| container_title | Canadian journal of chemistry |
| container_volume | 52 |
| creator | Brown, I. David Cutforth, Brent D Davies, Colin G Gillespie, Ronald J Ireland, Peter R Vekris, John E |
| description | The compound Hg
2.86
AsF
6
belongs to the tetragonal space group I4
1
/amd with lattice parameters a = 7.538(4) Å, c = 12.339(5) Å, and Z = 4. The structure was refined using 109 symmetry independent reflections by full matrix least-squares refinement to a final R value of 0.079. The structure may be described as consisting of octahedral AsF
6
−
ions arranged on a lattice which contains linear, non-intersecting channels in two mutually perpendicular directions. Within these channels are infinite chains of mercury atoms, each with a formal charge of +0.35, and with a mercury-mercury distance of 2.64(1) Å. |
| doi_str_mv | 10.1139/v74-124 |
| format | article |
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2.86
AsF
6
belongs to the tetragonal space group I4
1
/amd with lattice parameters a = 7.538(4) Å, c = 12.339(5) Å, and Z = 4. The structure was refined using 109 symmetry independent reflections by full matrix least-squares refinement to a final R value of 0.079. The structure may be described as consisting of octahedral AsF
6
−
ions arranged on a lattice which contains linear, non-intersecting channels in two mutually perpendicular directions. Within these channels are infinite chains of mercury atoms, each with a formal charge of +0.35, and with a mercury-mercury distance of 2.64(1) Å.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v74-124</identifier><language>eng ; jpn</language><publisher>Ottawa, Canada: NRC Research Press</publisher><ispartof>Canadian journal of chemistry, 1974-03, Vol.52 (5), p.791-793</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Brown, I. David</creatorcontrib><creatorcontrib>Cutforth, Brent D</creatorcontrib><creatorcontrib>Davies, Colin G</creatorcontrib><creatorcontrib>Gillespie, Ronald J</creatorcontrib><creatorcontrib>Ireland, Peter R</creatorcontrib><creatorcontrib>Vekris, John E</creatorcontrib><title>Alchemists' Gold, Hg2.86 Asf6; An X-Ray Crystallographic Study of A Novel Disordered Mercury Compound Containing Metallically Bonded Infinite Cations</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>The compound Hg
2.86
AsF
6
belongs to the tetragonal space group I4
1
/amd with lattice parameters a = 7.538(4) Å, c = 12.339(5) Å, and Z = 4. The structure was refined using 109 symmetry independent reflections by full matrix least-squares refinement to a final R value of 0.079. The structure may be described as consisting of octahedral AsF
6
−
ions arranged on a lattice which contains linear, non-intersecting channels in two mutually perpendicular directions. Within these channels are infinite chains of mercury atoms, each with a formal charge of +0.35, and with a mercury-mercury distance of 2.64(1) Å.</description><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1974</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp1kM1KAzEUhYMoWKv4ClkpiFPz18wMrsZR20JV8AfcDekkaVOmyZBMC_Mgvq8pduvm3ns43z2LA8AlRiOMaX63S1mCCTsCA8wylFCS42MwQAhlCUOMnIKzENZRpoiMB-CnaOqV2pjQhWs4cY28hdMlGWUcFkHze1hY-J28ix6Wvg-daBq39KJdmRp-dFvZQ6dhAV_dTjXw0QTnpfJKwhfl662PT27Tuq2V8bCdMNbYZfT2MaaOo4cPzsrIz6yOZqdgKTrjbDgHJ1o0QV0c9hB8PT99ltNk_jaZlcU8WWNKdKJJluM0zemCEL5AQiBdp4SmTCPFFUK5VhhzJrPxmOV8TBHPuNZCqQVVUhBEh-DmL9f62qughK9XVevNRvi-wqjaF1rFQqtYaISv_ocPUNVKTX8B_g92HQ</recordid><startdate>19740301</startdate><enddate>19740301</enddate><creator>Brown, I. David</creator><creator>Cutforth, Brent D</creator><creator>Davies, Colin G</creator><creator>Gillespie, Ronald J</creator><creator>Ireland, Peter R</creator><creator>Vekris, John E</creator><general>NRC Research Press</general><scope/></search><sort><creationdate>19740301</creationdate><title>Alchemists' Gold, Hg2.86 Asf6; An X-Ray Crystallographic Study of A Novel Disordered Mercury Compound Containing Metallically Bonded Infinite Cations</title><author>Brown, I. David ; Cutforth, Brent D ; Davies, Colin G ; Gillespie, Ronald J ; Ireland, Peter R ; Vekris, John E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j132f-f28917793b226b0aa0fc72374f0e6e009fe1164d855496530686ffaeeb3eda203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1974</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brown, I. David</creatorcontrib><creatorcontrib>Cutforth, Brent D</creatorcontrib><creatorcontrib>Davies, Colin G</creatorcontrib><creatorcontrib>Gillespie, Ronald J</creatorcontrib><creatorcontrib>Ireland, Peter R</creatorcontrib><creatorcontrib>Vekris, John E</creatorcontrib><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brown, I. David</au><au>Cutforth, Brent D</au><au>Davies, Colin G</au><au>Gillespie, Ronald J</au><au>Ireland, Peter R</au><au>Vekris, John E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Alchemists' Gold, Hg2.86 Asf6; An X-Ray Crystallographic Study of A Novel Disordered Mercury Compound Containing Metallically Bonded Infinite Cations</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1974-03-01</date><risdate>1974</risdate><volume>52</volume><issue>5</issue><spage>791</spage><epage>793</epage><pages>791-793</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><abstract>The compound Hg
2.86
AsF
6
belongs to the tetragonal space group I4
1
/amd with lattice parameters a = 7.538(4) Å, c = 12.339(5) Å, and Z = 4. The structure was refined using 109 symmetry independent reflections by full matrix least-squares refinement to a final R value of 0.079. The structure may be described as consisting of octahedral AsF
6
−
ions arranged on a lattice which contains linear, non-intersecting channels in two mutually perpendicular directions. Within these channels are infinite chains of mercury atoms, each with a formal charge of +0.35, and with a mercury-mercury distance of 2.64(1) Å.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v74-124</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1974-03, Vol.52 (5), p.791-793 |
| issn | 0008-4042 1480-3291 |
| language | eng ; jpn |
| recordid | cdi_nrcresearch_primary_10_1139_v74_124 |
| source | EZB Electronic Journals Library |
| title | Alchemists' Gold, Hg2.86 Asf6; An X-Ray Crystallographic Study of A Novel Disordered Mercury Compound Containing Metallically Bonded Infinite Cations |
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