Photochemistry of oxalate esters as a route to free radicals. Decay routes of crowded free radicals

Photolysis of suitable oxalate esters leads to alkyl radicals which in the case of di- and tri-tert-butylmethyl abstract hydrogen and for triisopropylmethyl-d 18 gives an esr spectrum consistent with the 'cogwheel' conformation for this species.

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Published in:Canadian journal of chemistry 1977-09, Vol.55 (18), p.3349-3350
Main Authors: Içli, Siddik, Nowlan, Vincent J, Rahimi, Parviz M, Thankachan, Chacko, Tidwell, Thomas T
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Language:English
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container_end_page 3350
container_issue 18
container_start_page 3349
container_title Canadian journal of chemistry
container_volume 55
creator Içli, Siddik
Nowlan, Vincent J
Rahimi, Parviz M
Thankachan, Chacko
Tidwell, Thomas T
description Photolysis of suitable oxalate esters leads to alkyl radicals which in the case of di- and tri-tert-butylmethyl abstract hydrogen and for triisopropylmethyl-d 18 gives an esr spectrum consistent with the 'cogwheel' conformation for this species.
doi_str_mv 10.1139/v77-468
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ispartof Canadian journal of chemistry, 1977-09, Vol.55 (18), p.3349-3350
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title Photochemistry of oxalate esters as a route to free radicals. Decay routes of crowded free radicals
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