Electron spin resonance study of the structure of some σ disulfur radical cations

The radical cations generated by exposure to 60 Co γ rays, at 77 K. of dilute solutions of 1,4-dithiane, 1,5-dithiacyclooctane, and thiirane in freon matrices, have been investigated by ESR spectroscopy. The relation between the g iso value and the SS σ bond length is studied quantitatively.

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Bibliographic Details
Published in:Canadian journal of chemistry 1988-12, Vol.66 (12), p.3050-3055
Main Authors: Bonazzola, L, Michaut, J.P, Roncin, J
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Electron resonance and relaxation
Exact sciences and technology
Molecular properties and interactions with photons
Physics
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Description
Summary:The radical cations generated by exposure to 60 Co γ rays, at 77 K. of dilute solutions of 1,4-dithiane, 1,5-dithiacyclooctane, and thiirane in freon matrices, have been investigated by ESR spectroscopy. The relation between the g iso value and the SS σ bond length is studied quantitatively.
ISSN:0008-4042
1480-3291
DOI:10.1139/v88-472