The infrared and Raman spectra of methoxycarbonyl and thiomethoxycarbonyl isocyanates

The gas phase infrared and liquid phase Raman spectra of the title compounds have been recorded and vibrational analyses performed. The spectra show evidence for the presence in both the liquid and vapour phases of two rotational isomers: cisoid-Z and transoid-Z with reference to orientation of isoc...

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Bibliographic Details
Published in:Canadian journal of chemistry 1993-10, Vol.71 (10), p.1627-1631
Main Authors: Balfour, Walter J, Fougere, Scott G, Klapstein, Dieter, Nau, Werner M
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Infrared spectra
Molecular properties and interactions with photons
Molecular spectra
Physics
Raman and rayleigh spectra (including optical scattering)
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Summary:The gas phase infrared and liquid phase Raman spectra of the title compounds have been recorded and vibrational analyses performed. The spectra show evidence for the presence in both the liquid and vapour phases of two rotational isomers: cisoid-Z and transoid-Z with reference to orientation of isocyanato and methyl groups relative to the carbonyl group.
ISSN:0008-4042
1480-3291
DOI:10.1139/v93-203