A Discrete Molecule and a 1D Coordination Polymer of Cadmium(II): Preparation, Structures, and Properties of [Cd(L1)2(NO3)2(CH3OH)] and {[Cd(L2)(CH3COO)2]·(CH3OH)}∞ (L1 = (4‐Py)–CH=N–C10H6–NH2; L2 = (3‐Py)–CH=N–C10H6–N=CH–(3‐Py))

An asymmetric ligand, (4‐py)–CH=N–C10H6–NH2 (L1), was prepared from 4‐pyridinecarboxaldehyde and 1,5‐diaminonaphthalene. The ligand L1 reacted with Cd(NO3)2·4H2O in methanol to give a discrete molecular complex, [Cd(L1)2(NO3)2(CH3OH)] (1). In addition, a 1D cadmium coordination polymer possessing a...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2019, 40(10), , pp.958-962
Main Authors: Ryu, Jihwan, Lee, Gang Min, Lee, Soon W.
Format: Article
Language:English
Subjects:
Amine group
Asymmetric ligand
Cadmium coordination polymer
Pyridyl–amine ligand
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Summary:An asymmetric ligand, (4‐py)–CH=N–C10H6–NH2 (L1), was prepared from 4‐pyridinecarboxaldehyde and 1,5‐diaminonaphthalene. The ligand L1 reacted with Cd(NO3)2·4H2O in methanol to give a discrete molecular complex, [Cd(L1)2(NO3)2(CH3OH)] (1). In addition, a 1D cadmium coordination polymer possessing a methanol molecule, {[Cd(L2)(CH3COO)2]·(CH3OH)}∞ (2), was prepared from a symmetric ligand (L2 = (3‐py)–CH=N–C10H6–N=CH–(3‐py)) and Cd(OAc)2·2H2O. Packing diagram perpendicular to the [101] plane of compound 2.
ISSN:1229-5949
0253-2964
1229-5949
DOI:10.1002/bkcs.11853