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Solvent‐Ratio Dependency of Polymorphism of Silver(I) Complexes Containing 1,2,3‐Tris(Isoniconitoyloxy)Benzene
Self‐assembly of AgClO4 with 1,2,3‐tris(isonicotinoyloxy)benzene (L) in a mixture of ethanol and acetone in a 1:1 volume ratio in refrigerator afforded concomitantly two kinds of thin‐ and block‐shaped colorless crystals consisting of {[Ag(L)]ClO4·0.5CH3CH2OH} n and {[Ag(L)]ClO4·0.5CH3CH2OH·2Me2CO}...
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| Published in: | Bulletin of the Korean Chemical Society 2019, 40(11), , pp.1068-1075 |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c3430-5040f7f9ce2f4b46c9214ddfc7140fb45469d209afcb94307e665e5e8fc0b00a3 |
| container_end_page | 1075 |
| container_issue | 11 |
| container_start_page | 1068 |
| container_title | Bulletin of the Korean Chemical Society |
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| creator | Jeong, Hyun Chul Noh, Tae Hwan |
| description | Self‐assembly of AgClO4 with 1,2,3‐tris(isonicotinoyloxy)benzene (L) in a mixture of ethanol and acetone in a 1:1 volume ratio in refrigerator afforded concomitantly two kinds of thin‐ and block‐shaped colorless crystals consisting of {[Ag(L)]ClO4·0.5CH3CH2OH}
n and {[Ag(L)]ClO4·0.5CH3CH2OH·2Me2CO}
n, respectively, in a 3:2 ratio. By contrast, self‐assembly at room temperature yielded thin crystals exclusively. At 5 °C, in particular, the self‐assembly in 3:1 and 1:2 ethanol/acetone solutions yielded thin‐ and block‐shaped crystals, respectively, suggesting that discrimination of the two products can be controlled by the solvent volume ratio and crystallization temperature. The products' crystal structures and physicochemical properties were fully characterized by means of single‐crystal X‐ray diffraction measurement, thermal analysis, and infrared (IR) data.
Two kinds of thin‐ and block‐shaped crystals have afforded simultaneously. |
| doi_str_mv | 10.1002/bkcs.11870 |
| format | article |
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n and {[Ag(L)]ClO4·0.5CH3CH2OH·2Me2CO}
n, respectively, in a 3:2 ratio. By contrast, self‐assembly at room temperature yielded thin crystals exclusively. At 5 °C, in particular, the self‐assembly in 3:1 and 1:2 ethanol/acetone solutions yielded thin‐ and block‐shaped crystals, respectively, suggesting that discrimination of the two products can be controlled by the solvent volume ratio and crystallization temperature. The products' crystal structures and physicochemical properties were fully characterized by means of single‐crystal X‐ray diffraction measurement, thermal analysis, and infrared (IR) data.
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n and {[Ag(L)]ClO4·0.5CH3CH2OH·2Me2CO}
n, respectively, in a 3:2 ratio. By contrast, self‐assembly at room temperature yielded thin crystals exclusively. At 5 °C, in particular, the self‐assembly in 3:1 and 1:2 ethanol/acetone solutions yielded thin‐ and block‐shaped crystals, respectively, suggesting that discrimination of the two products can be controlled by the solvent volume ratio and crystallization temperature. The products' crystal structures and physicochemical properties were fully characterized by means of single‐crystal X‐ray diffraction measurement, thermal analysis, and infrared (IR) data.
Two kinds of thin‐ and block‐shaped crystals have afforded simultaneously.</description><subject>Coordination polymers</subject><subject>Polymorphism</subject><subject>Silver(I) complexes</subject><subject>Solvent effect</subject><subject>화학</subject><issn>1229-5949</issn><issn>0253-2964</issn><issn>1229-5949</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kL1OwzAUhS0EEqWw8AQZW9QU23GSZizhL6ISqC2zlTh2MU3syo6gYeIReEaeBLdhYGK4OvfqfucMB4BzBMcIQnxZrJkdIzSJ4QHoIYwTP0xIcvhnPwYn1r46No5x2ANmoas3rprvz6953kjtXfMNVyVXrPW08J501dbabF6krXf3QjraDLKhl-p6U_Ett25TTS6VVCsPjfAocFFLI-0gs1pJ5qbRbaW37fCKqw-u-Ck4Enll-dmv9sHz7c0yvfdnj3dZOp35LCAB9ENIoIhFwjgWpCARSzAiZSlYjNyjICGJkhLDJBesSJwh5lEU8pBPBIMFhHnQB8MuVxlB10xSncu9rjRdGzqdLzMaYYwmiDj2omOZ0dYaLujGyDo3LUWQ7pqlu2bpvlkHow5-lxVv_yHp1UO66Dw_K2h-Cw</recordid><startdate>201911</startdate><enddate>201911</enddate><creator>Jeong, Hyun Chul</creator><creator>Noh, Tae Hwan</creator><general>Wiley‐VCH Verlag GmbH & Co. KGaA</general><general>대한화학회</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ACYCR</scope></search><sort><creationdate>201911</creationdate><title>Solvent‐Ratio Dependency of Polymorphism of Silver(I) Complexes Containing 1,2,3‐Tris(Isoniconitoyloxy)Benzene</title><author>Jeong, Hyun Chul ; Noh, Tae Hwan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3430-5040f7f9ce2f4b46c9214ddfc7140fb45469d209afcb94307e665e5e8fc0b00a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Coordination polymers</topic><topic>Polymorphism</topic><topic>Silver(I) complexes</topic><topic>Solvent effect</topic><topic>화학</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jeong, Hyun Chul</creatorcontrib><creatorcontrib>Noh, Tae Hwan</creatorcontrib><collection>CrossRef</collection><collection>Korean Citation Index</collection><jtitle>Bulletin of the Korean Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jeong, Hyun Chul</au><au>Noh, Tae Hwan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent‐Ratio Dependency of Polymorphism of Silver(I) Complexes Containing 1,2,3‐Tris(Isoniconitoyloxy)Benzene</atitle><jtitle>Bulletin of the Korean Chemical Society</jtitle><date>2019-11</date><risdate>2019</risdate><volume>40</volume><issue>11</issue><spage>1068</spage><epage>1075</epage><pages>1068-1075</pages><issn>1229-5949</issn><issn>0253-2964</issn><eissn>1229-5949</eissn><abstract>Self‐assembly of AgClO4 with 1,2,3‐tris(isonicotinoyloxy)benzene (L) in a mixture of ethanol and acetone in a 1:1 volume ratio in refrigerator afforded concomitantly two kinds of thin‐ and block‐shaped colorless crystals consisting of {[Ag(L)]ClO4·0.5CH3CH2OH}
n and {[Ag(L)]ClO4·0.5CH3CH2OH·2Me2CO}
n, respectively, in a 3:2 ratio. By contrast, self‐assembly at room temperature yielded thin crystals exclusively. At 5 °C, in particular, the self‐assembly in 3:1 and 1:2 ethanol/acetone solutions yielded thin‐ and block‐shaped crystals, respectively, suggesting that discrimination of the two products can be controlled by the solvent volume ratio and crystallization temperature. The products' crystal structures and physicochemical properties were fully characterized by means of single‐crystal X‐ray diffraction measurement, thermal analysis, and infrared (IR) data.
Two kinds of thin‐ and block‐shaped crystals have afforded simultaneously.</abstract><cop>Weinheim</cop><pub>Wiley‐VCH Verlag GmbH & Co. KGaA</pub><doi>10.1002/bkcs.11870</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Bulletin of the Korean Chemical Society, 2019, 40(11), , pp.1068-1075 |
| issn | 1229-5949 0253-2964 1229-5949 |
| language | eng |
| recordid | cdi_nrf_kci_oai_kci_go_kr_ARTI_6221814 |
| source | Wiley-Blackwell Read & Publish Collection |
| subjects | Coordination polymers Polymorphism Silver(I) complexes Solvent effect 화학 |
| title | Solvent‐Ratio Dependency of Polymorphism of Silver(I) Complexes Containing 1,2,3‐Tris(Isoniconitoyloxy)Benzene |
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