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Effect of ZnO on physical and optical properties of bismuth borate glasses

This paper presents the results and observations obtained from a study of the effects of zinc oxide on the optical properties of B 2 O 3 -Bi 2 O 3 -ZnO glasses. In this study, we prepared glasses with the composition, 2xZnO-(50-x)[B 2 O 3 ·Bi 2 O 3 ], (x=0, 5, 10, 15), and analyzed their physical, t...

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Bibliographic Details
Published in:Electronic materials letters 2009, 5(4), , pp.209-212
Main Authors: Kim, Nam Jin, La, Young Hoon, Im, Sang Hyeok, Han, Won-Tack, Ryu, Bong Ki
Format: Article
Language:English
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Summary:This paper presents the results and observations obtained from a study of the effects of zinc oxide on the optical properties of B 2 O 3 -Bi 2 O 3 -ZnO glasses. In this study, we prepared glasses with the composition, 2xZnO-(50-x)[B 2 O 3 ·Bi 2 O 3 ], (x=0, 5, 10, 15), and analyzed their physical, thermal and optical properties. The systematic variation in the density and molar volume in these glasses indicates the effect of ZnO on the glass structure. Differential thermal analysis (DTA) studies showed that the glass transition temperature (T g ) decreases from 423°C to 390°C as the content of ZnO increases. The values of the optical band gap and theoretical optical basicity are also investigated.
ISSN:1738-8090
2093-6788
DOI:10.3365/eml.2009.12.209