The effect of phase transition of methanol on the reaction rate in the alkylation of hydroquinone

• Published in: The Korean journal of chemical engineering 2009, 26(3), 120, pp.649-653
• Main Authors: Park, Jung Je, Lee, Soo Chool, Lee, Sang Sung, Jung, Suk Yong, Lee, Soo Jae, Kim, Jae Chang
• Format: Article
• Language: English
• Subjects: Biotechnology; Catalysis; Chemistry; Chemistry and Materials Science; Industrial Chemistry; Industrial Chemistry/Chemical Engineering; Materials Science; Reaction Engineering; 화학공학
• ISSN: 0256-1115; 1975-7220
• DOI: 10.1007/s11814-009-0108-8

An O-alkylation reaction of hydroquinone with excess methanol was carried out by using alkaline metal ion-exchanged zeolite catalysts at various phases of methanol in a slurry type reactor. The amount of methanol, used as a methylating agent and also a solvent, significantly affected the reaction rate. When the amount of methanol was decreased from 2 mol to 0.6 mol, the reaction rate was increased more than nine times. These changes in the reaction rate could be explained by the pressure change and the phase transition of the reactant, methanol, depending on the temperature and the elimination of a diffusion limitation of reactants through the zeolite pores in a gas phase condition. Thus, higher than 89% selectivity to 4-methoxyphenol was obtained at 80% conversion of hydroquinone at a gas phase reaction condition using 1 mol of methanol for 2 hours.