Catalytic performance of pyridinium salt ionic liquid in the synthesis of cyclic carbonate from carbon dioxide and butyl glycidyl ether

The catalytic performance of pyridinium salt ionic liquids in the reaction of butyl glycidyl ether and carbon dioxide was investigated in this study. The catalytic activity was studied in a batch reactor with different 1-alkylpyridinium salt ionic liquids at 60–140°C. The conversion of butyl glycidy...

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Bibliographic Details
Published in:The Korean journal of chemical engineering 2008, 25(3), 114, pp.471-473
Main Authors: Ju, Hye-Young, Ahn, Ji-Yeon, Manju, Mamparambath-Dharman, Kim, Kyung-Hoon, Park, Dae-Won
Format: Article
Language:English
Subjects:
Biotechnology
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry
Industrial Chemistry/Chemical Engineering
Materials Science
Reaction Engineering
화학공학
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Summary:The catalytic performance of pyridinium salt ionic liquids in the reaction of butyl glycidyl ether and carbon dioxide was investigated in this study. The catalytic activity was studied in a batch reactor with different 1-alkylpyridinium salt ionic liquids at 60–140°C. The conversion of butyl glycidyl ether was affected by the structure of the ionic liquid; the one with the cation of bulkier alkyl chain length showed better reactivity. The effect of carbon dioxide pressure, reaction temperature and zinc bromide co-catalyst on this reaction was also discussed.
ISSN:0256-1115
1975-7220
DOI:10.1007/s11814-008-0080-8