CdII MOFs Constructed Using Succinate and Bipyridyl Ligands: Photoluminescence and Heterogeneous Catalytic Activity

Four CdII MOFs, [Cd2(μ-succinate)2(H2O)2]·H2O (1A), [Cd2(μ-succinate)2(μ-4,4'-bpy)2]·H2O (1B), [{Cd2(μ- succinate)2}(μ-bpa)2{Cd(H2O)2}(NO3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp)2]·2H2O (3), with various bipyridyl ligands (4,4'-bipyridine (4,4'-bpy), 1,2-bis(4-pyridyl)ethane (bpa), an...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2014, 35(6), , pp.1777-1783
Main Authors: Myoung Mi Lee, 김하영, In Hong Hwang, Jeong Mi Bae, 김철, Chul-Hyun Yo, 김영미, 김성진
Format: Article
Language:English
Subjects:
화학
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Summary:Four CdII MOFs, [Cd2(μ-succinate)2(H2O)2]·H2O (1A), [Cd2(μ-succinate)2(μ-4,4'-bpy)2]·H2O (1B), [{Cd2(μ- succinate)2}(μ-bpa)2{Cd(H2O)2}(NO3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp)2]·2H2O (3), with various bipyridyl ligands (4,4'-bipyridine (4,4'-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII–(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined. KCI Citation Count: 10
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2014.35.6.1777