Chromium(III) Complex Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Electrochemical Studies

The synthesis, X-ray crystallography, spectroscopic (IR, UV-vis), and electrochemical properties of the title compound, [H3O][Cr(dipic)2] [H3O+.Cl−] (1), (H2dipic = 2,6-pyridinedicarboxylic acid), are reported. This complex crystallizes in the monoclinic space group Cc with a = 14.9006(10) Å, b = 12...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2013, 34(10), , pp.3093-3097
Main Authors: Ghasemi, Khaled, Rezvani, Ali Reza, Razak, Ibrahim Abdul, Moghimi, Abolghasem, Ghasemi, Fatemeh, Rosli, Mohd Mustaqim
Format: Article
Language:English
Subjects:
화학
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Summary:The synthesis, X-ray crystallography, spectroscopic (IR, UV-vis), and electrochemical properties of the title compound, [H3O][Cr(dipic)2] [H3O+.Cl−] (1), (H2dipic = 2,6-pyridinedicarboxylic acid), are reported. This complex crystallizes in the monoclinic space group Cc with a = 14.9006(10) Å, b = 12.2114(8) Å, c = 8.6337(6) Å, α = 90.00°, β = 92.7460(10)°, γ = 90.00°, and V = 1569.16(18) Å3 with Z = 4. The hydrogen bonding and noncovalent interactions play roles in the stabilization of the structure. In order to gain a better understanding of the most important geometrical parameters in the structure of the complex, atoms in molecules (AIM) method at B3LYP/6-31G level of theory has been employed. KCI Citation Count: 6
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2013.34.10.3093