Synthesis, Structure and Thermal Properties of Bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO)

A novel energetic compound, bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of BFFO·H2O is monoclinic, space group...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2012, 33(10), , pp.3317-3320
Main Authors: Zhou, Yanshui, Xu, Kangzhen, Wang, Bozhou, Zhang, Hang, Qiu, Qianqian, Zhao, Fengqi
Format: Article
Language:English
Subjects:
화학
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Summary:A novel energetic compound, bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of BFFO·H2O is monoclinic, space group P2(1)/c with crystal parameters of a = 9.324(4) Å, b = 9.727(4) Å, c = 10.391(4) Å, β = 106.305(6)°, V = 904.5(6) Å3, Z = 4, μ = 0.17 mm−1, F(000) = 512 and Dc = 1.866 g cm−3. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties. KCI Citation Count: 11
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2012.33.10.3317