Synthesis of Ferrocenyl and Diphenyl Substituted Bispyridino-18-Crown-6 Ether for Chiral Recognition

The article reports the synthesis of a novel bispyridino-18-crown-6 ether, 7-{[(5S,15S)-5,15-diphenyl-3,6,14,17-tetraoxa-23,24-diazatricyclo[17.3.1.18,12]tetracosa-1(23),8(24),9,11,19,21-hexaen-10-yl]oxy}heptylferrocenamide 6, bearing the C2-symmetric diphenyl substituents as chiral barriers and the...

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Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2007, 28(11), , pp.2015-2019
Main Authors: Sunjin Jo, 진영읍, Jaehong Kim, Hongsuk Suh
Format: Article
Language:English
Subjects:
화학
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Summary:The article reports the synthesis of a novel bispyridino-18-crown-6 ether, 7-{[(5S,15S)-5,15-diphenyl-3,6,14,17-tetraoxa-23,24-diazatricyclo[17.3.1.18,12]tetracosa-1(23),8(24),9,11,19,21-hexaen-10-yl]oxy}heptylferrocenamide 6, bearing the C2-symmetric diphenyl substituents as chiral barriers and the ferrocenyl groups serving as an electrochemical sensor, and its electrochemical study with D- and L-AlaOMeHCl as the guest by cyclovoltametry. KCI Citation Count: 3
ISSN:0253-2964
1229-5949
DOI:10.5012/bkcs.2007.28.11.2015