Radiolytic synthesis of Pd-M (M = Ag, Ni, and Cu)/C catalyst and their use in Suzuki-type and Heck-type reaction

Carbon-supported bimetallic Pd-M (M = Ag, Ni, and Cu) nanoparticles were synthesized by γ-irradiation at room temperature without reducing agents, and then were loaded on carbon (producing Pd/C and Pd-M/C), which was confirmed by TEM, STEM, TEM-EDXS, ICP-AES and XRD data. The Pd/C and Pd-M/C materia...

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Bibliographic Details
Published in:Journal of industrial and engineering chemistry (Seoul, Korea) 2008, 14(4), , pp.449-456
Main Authors: Kim, Sang-Jun, Oh, Seong-Dae, Lee, Seungho, Choi, Seong-Ho
Format: Article
Language:English
Subjects:
Catalyst
Heck-type reaction
Pd-Ag/C
Pd-Cu/C
Pd-Ni/C
Pd/C
Suzuki-type reaction
γ-Irradiation
화학공학
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Summary:Carbon-supported bimetallic Pd-M (M = Ag, Ni, and Cu) nanoparticles were synthesized by γ-irradiation at room temperature without reducing agents, and then were loaded on carbon (producing Pd/C and Pd-M/C), which was confirmed by TEM, STEM, TEM-EDXS, ICP-AES and XRD data. The Pd/C and Pd-M/C materials were applied as catalyst in Suzuki- and Heck-type reactions in EtOH and in acetonitrile, respectively. The Pd-Cu/C showed high catalytic efficiency in the Suzuki- and Heck-type reaction.
ISSN:1226-086X
1876-794X
DOI:10.1016/j.jiec.2008.02.006