Acetonitrile coordination to silver(I) ions of 1‐D coordination polymers with 1,3‐di(nicotinoyloxy)‐2‐methylenepropane

The fluorescent molecule 1,3‐di(nicotinoyloxy)‐2‐methylenepropane (L) can be a good candidate for construction of coordination polymers with photoluminescence (PL) properties. Self‐assembly of silver(I) hexafluorophosphate with this ligand in a mixture of methanol and dichloromethane produced a 1‐D...

Full description

Saved in:
Bibliographic Details
Published in:Bulletin of the Korean Chemical Society 2022, 43(4), , pp.602-608
Main Authors: Jo, Seong Min, Noh, Tae Hwan
Format: Article
Language:English
Subjects:
acetonitrile coordination
coordination polymers
intramolecular interactions
silver(I) compounds
solvent media
화학
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The fluorescent molecule 1,3‐di(nicotinoyloxy)‐2‐methylenepropane (L) can be a good candidate for construction of coordination polymers with photoluminescence (PL) properties. Self‐assembly of silver(I) hexafluorophosphate with this ligand in a mixture of methanol and dichloromethane produced a 1‐D helical coordination polymer consisting of [Ag(L)](PF6), whereas crystallization from an acetonitrile‐based medium afforded a 1‐D sinusoidal coordination polymer consisting of [Ag(L)(CH3CN)2](PF6) having intramolecular argentophilic Ag∙∙∙Ag and π∙∙∙π interactions arising from the eclipsed conformation of L. These findings suggest that the final structures of the two products can be controlled by the reaction solvent media rather than the crystallization method or concentration. The physicochemical properties of the present silver(I) compounds were fully characterized by means of infrared spectroscopy, thermogravimetric analysis/differential scanning calorimetry, PL, single‐crystal x‐ray diffraction (XRD), and powder‐XRD measurements.
ISSN:1229-5949
0253-2964
1229-5949
DOI:10.1002/bkcs.12500