Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage

A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2010-10, Vol.46 (39), p.7352-7354
Main Authors: Zhao, Dan, Yuan, Daqiang, Krishna, Rajamani, van Baten, Jasper M, Zhou, Hong-Cai
Format: Article
Language:English
Subjects:
ADSORPTION
GASES
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MOLECULAR SIEVES
NANOSCIENCE AND NANOTECHNOLOGY
NANOSTRUCTURES
POROUS MATERIALS
SEPARATION PROCESSES
TEMPERATURE DEPENDENCE
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Description
Summary:A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc02771e