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Influence of solid corrosion by-products on the consumption of dissolved oxygen in copper pipes
Research on corrosion of copper pipes has given little consideration to the influence of solid corrosion by-products on the processes occurring at the metal–liquid interface. Consequently, the effect of such solid phases on the rate of dissolved oxygen (DO) consumption remains poorly understood. In-...
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Published in: | Corrosion science 2009-05, Vol.51 (5), p.1030-1037 |
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container_title | Corrosion science |
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creator | Vargas, Ignacio T. Alsina, Marco A. Pastén, Pablo A. Pizarro, Gonzalo E. |
description | Research on corrosion of copper pipes has given little consideration to the influence of solid corrosion by-products on the processes occurring at the metal–liquid interface. Consequently, the effect of such solid phases on the rate of dissolved oxygen (DO) consumption remains poorly understood. In-situ experiments were performed in copper pipes under different carbonate concentrations and ageing times. Our results show that the amount of solid corrosion by-products and concentration of hydrogen ions affect the rate of DO consumption during stagnation. Furthermore, our findings support the existing hypothesis that the available concentration of hydrogen ions, rather than DO, is the limiting factor for copper release into drinking water. |
doi_str_mv | 10.1016/j.corsci.2009.02.014 |
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(ANL), Argonne, IL (United States)</creatorcontrib><title>Influence of solid corrosion by-products on the consumption of dissolved oxygen in copper pipes</title><title>Corrosion science</title><description>Research on corrosion of copper pipes has given little consideration to the influence of solid corrosion by-products on the processes occurring at the metal–liquid interface. Consequently, the effect of such solid phases on the rate of dissolved oxygen (DO) consumption remains poorly understood. In-situ experiments were performed in copper pipes under different carbonate concentrations and ageing times. Our results show that the amount of solid corrosion by-products and concentration of hydrogen ions affect the rate of DO consumption during stagnation. Furthermore, our findings support the existing hypothesis that the available concentration of hydrogen ions, rather than DO, is the limiting factor for copper release into drinking water.</description><subject>A. Copper</subject><subject>AGING</subject><subject>Applied sciences</subject><subject>ATOMIC AND MOLECULAR PHYSICS</subject><subject>B. SEM</subject><subject>BY-PRODUCTS</subject><subject>C. Oxidation</subject><subject>C. Passive films</subject><subject>CARBONATES</subject><subject>COPPER</subject><subject>CORROSION</subject><subject>Corrosion environments</subject><subject>DISSOLVED GASES</subject><subject>DRINKING WATER</subject><subject>Exact sciences and technology</subject><subject>HYDROGEN IONS</subject><subject>HYPOTHESIS</subject><subject>Metals. 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subjects | A. Copper AGING Applied sciences ATOMIC AND MOLECULAR PHYSICS B. SEM BY-PRODUCTS C. Oxidation C. Passive films CARBONATES COPPER CORROSION Corrosion environments DISSOLVED GASES DRINKING WATER Exact sciences and technology HYDROGEN IONS HYPOTHESIS Metals. Metallurgy OXYGEN PIPES SOLIDS STAGNATION SUPPORTS |
title | Influence of solid corrosion by-products on the consumption of dissolved oxygen in copper pipes |
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