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When Function Follows Form: Effects of Donor Copolymer Side Chains on Film Morphology and BHJ Solar Cell Performance

Detailed structural organization in organic films are investigated using grazing incidence X‐ray scattering (GIXS) methods. The key structural features are revealed and the influence of specific side chain positions and shapes are characterized. A correlation between the fill factor (FF) of the corr...

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Published in:Advanced materials (Weinheim) 2010-12, Vol.22 (48), p.5468-5472
Main Authors: Szarko, Jodi M., Guo, Jianchang, Liang, Yongye, Lee, Byeongdu, Rolczynski, Brian S., Strzalka, Joseph, Xu, Tao, Loser, Stephen, Marks, Tobin J., Yu, Luping, Chen, Lin X.
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cited_by cdi_FETCH-LOGICAL-c5167-77af34b361047cdb12bb85f66219a60f78c8003936086888a4b22fa7117f079f3
cites cdi_FETCH-LOGICAL-c5167-77af34b361047cdb12bb85f66219a60f78c8003936086888a4b22fa7117f079f3
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container_issue 48
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container_title Advanced materials (Weinheim)
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creator Szarko, Jodi M.
Guo, Jianchang
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Loser, Stephen
Marks, Tobin J.
Yu, Luping
Chen, Lin X.
description Detailed structural organization in organic films are investigated using grazing incidence X‐ray scattering (GIXS) methods. The key structural features are revealed and the influence of specific side chain positions and shapes are characterized. A correlation between the fill factor (FF) of the corresponding device and the tightness of the polymer chain stacking inspires a new set of structural parameters for design of materials to optimize device efficiency.
doi_str_mv 10.1002/adma.201002687
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source Wiley-Blackwell Read & Publish Collection
subjects conducting polymers
conjugated polymers
COPOLYMERS
MORPHOLOGY
photovoltaic devices
Polymers - chemistry
Scattering, Small Angle
SOLAR CELLS
SOLAR ENERGY
structure-property relationships
title When Function Follows Form: Effects of Donor Copolymer Side Chains on Film Morphology and BHJ Solar Cell Performance
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