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Role of Water in the Ion Selectivity of Niobate-Based Octahedral Molecular Sieves
The role of occluded water in ion exchange selectivity is examined in a class of molecular sieves named Sandia Octahedral Molecular Sieves (SOMS: Na2Nb2- x M x O6- x (OH) x ·H2O (i.e., M = Ti; 0 < x < 0.4)). SOMS exhibit a high selectivity for divalent cations only when the framework Nb(5+) a...
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Published in: | Journal of physical chemistry. C 2007-09, Vol.111 (35), p.13212-13221 |
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Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The role of occluded water in ion exchange selectivity is examined in a class of molecular sieves named Sandia Octahedral Molecular Sieves (SOMS: Na2Nb2- x M x O6- x (OH) x ·H2O (i.e., M = Ti; 0 < x < 0.4)). SOMS exhibit a high selectivity for divalent cations only when the framework Nb(5+) are substituted by M(4+) atoms. Vibrational dynamics of the water molecules with varying charge balancing cations and M atoms are studied by inelastic neutron scattering (INS) measurements and 1H MAS NMR and correlated to density functional theory and molecular dynamics data. The experimental INS spectra were compared with those of ice Ih to characterize the changes induced by confinement on the occluded H2O and the resulting hydrogen-bonding network. Data indicates that, with increasing M(4+) content and divalent ion exchange, the trend of occluded water molecules is to change from extended rigid ice-like networks to restored bulk-like arrangements with increased solvation effects on the channel charge-balancing cations. |
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ISSN: | 1932-7447 1932-7455 |
DOI: | 10.1021/jp073969j |