NIR-Selective electrochromic heteromaterial frameworks: a platform to understand mesoscale transport phenomena in solid-state electrochemical devices

We report here the first solid-state, NIR-selective electrochromic devices. Critical to device performance is the arrangement of nanocrystal-derived electrodes into heteromaterial frameworks, where hierarchically porous ITO nanocrystal active layers are infiltrated by an ion-conducting polymer elect...

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Published in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2014-01, Vol.2 (17), p.3328
Main Authors: Williams, Teresa E., Chang, Christina M., Rosen, Evelyn L., Garcia, Guillermo, Runnerstrom, Evan L., Williams, Bradley L., Koo, Bonil, Buonsanti, Raffaella, Milliron, Delia J., Helms, Brett A.
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cited_by cdi_FETCH-LOGICAL-c324t-c4e8eaaaed2593d4795e663306873ca1c0b1d3bf1dd5fbc41336308c56ceb81c3
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container_issue 17
container_start_page 3328
container_title Journal of materials chemistry. C, Materials for optical and electronic devices
container_volume 2
creator Williams, Teresa E.
Chang, Christina M.
Rosen, Evelyn L.
Garcia, Guillermo
Runnerstrom, Evan L.
Williams, Bradley L.
Koo, Bonil
Buonsanti, Raffaella
Milliron, Delia J.
Helms, Brett A.
description We report here the first solid-state, NIR-selective electrochromic devices. Critical to device performance is the arrangement of nanocrystal-derived electrodes into heteromaterial frameworks, where hierarchically porous ITO nanocrystal active layers are infiltrated by an ion-conducting polymer electrolyte with mesoscale periodicity. Enhanced coloration efficiency and transport are realized over unarchitectured electrodes in devices, paving the way towards new smart windows technologies.
doi_str_mv 10.1039/c3tc32247e
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title NIR-Selective electrochromic heteromaterial frameworks: a platform to understand mesoscale transport phenomena in solid-state electrochemical devices
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