Thermoelectric and electrical transport properties of Mg2Si multi-doped with Sb, Al and Zn

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-09, Vol.3 (39), p.19774-19782
• Main Authors: Zhao, Jianbao, Liu, Zhenxian, Reid, Joel, Takarabe, Kenichi, Iida, Tsutomu, Wang, Bosen, Yoshiya, Uwatoko, Tse, John S
• Format: Article
• Language: English
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c5ta03751d

Enhanced thermoelectric and electrical transport properties of Mg 2 Si-based thermoelectric materials have been achieved by multi-doping with Sb, Al and Zn. Results on the investigation of the electrical transport and thermoelectric properties of multi-doped samples prepared using the spark plasma sintering technique are reported. Synchrotron radiation powder X-ray diffraction was used to characterize the structures of the doped samples. The electrical transport properties were determined from mid-infrared reflectivities, Hall effect and conventional quasi-four probe conductivity measurements. Using the electron concentrations ( N ) determined from the Hall coefficients, the effective masses ( m *) were calculated from the frequency of the plasma edge ( ω P ) of the infrared reflectivities. The thermoelectric performance and thermoelectric figure of merits ( ZT ) in the temperature range of 300 K to 900 K of the doped Mg 2 Si compounds were calculated from the measured temperature dependent electrical conductivity ( σ ), Seebeck coefficient ( S ), and thermal conductivity ( κ ). A maximum ZT of 0.964 was found for Sb0.5%Zn0.5% doped Mg 2 Si at 880 K. This value is comparable to those of PbTe based thermoelectric materials. A maximum ZT of 0.964 was found for Sb0.5%Zn0.5% doped Mg 2 Si, which is comparable to those of PbTe based thermoelectric materials.