Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance

Magnesium intercalated vanadium oxide xerogels, Mg0.1V2O5 · 2.35H2O and Mg0.2V2O5 · 2.46H2O were synthesized using an ion removal sol gel strategy. X-ray diffraction indicated lamellar ordering with turbostratic character. X-ray absorption spectroscopy indicated greater distortion of the vanadium-ox...

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Published in:Journal of the Electrochemical Society 2016-07, Vol.163 (9), p.A1941-A1943
Main Authors: Yin, Jiefu, Pelliccione, Christopher J., Lee, Shu Han, Takeuchi, Esther S., Takeuchi, Kenneth J., Marschilok, Amy C.
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Language:English
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battery
energy
ENERGY STORAGE
magnesium
spectroscopy
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container_end_page A1943
container_issue 9
container_start_page A1941
container_title Journal of the Electrochemical Society
container_volume 163
creator Yin, Jiefu
Pelliccione, Christopher J.
Lee, Shu Han
Takeuchi, Esther S.
Takeuchi, Kenneth J.
Marschilok, Amy C.
description Magnesium intercalated vanadium oxide xerogels, Mg0.1V2O5 · 2.35H2O and Mg0.2V2O5 · 2.46H2O were synthesized using an ion removal sol gel strategy. X-ray diffraction indicated lamellar ordering with turbostratic character. X-ray absorption spectroscopy indicated greater distortion of the vanadium-oxygen coordination environment in Mg0.2V2O5 · 2.46H2O. Elemental analysis after cycling in Li+ or Mg2+ based electrolytes revealed that the magnesium content was unchanged, indicating structural Mg2+ are retained. Furthermore, the Mg0.1V2O5 · 2.35H2O material displayed high voltage, energy density, and discharge/charge efficiency, indicating promise as a cathode material for future magnesium based batteries.
doi_str_mv 10.1149/2.0781609jes
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source Institute of Physics:Jisc Collections:IOP Publishing Read and Publish 2024-2025 (Reading List)
subjects battery
energy
ENERGY STORAGE
magnesium
spectroscopy
title Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance
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