Systematic Study of Open‐Shell Trigonal Pyramidal Transition‐Metal Complexes with a Rigid‐Ligand Scaffold

A family of distorted trigonal pyramidal transition‐metal complexes [MII(N3N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single‐molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibit...

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Bibliographic Details
Published in:Chemistry : a European journal 2017-03, Vol.23 (15), p.3548-3552
Main Authors: Pinkowicz, Dawid, Birk, Francisco J., Magott, Michał, Schulte, Kelsey, Dunbar, Kim R.
Format: Article
Language:English
Subjects:
Analogue
Chemical bonds
Chemistry
Cobalt
coordination chemistry
Distortion
Electronics
Iron
Magnetic anisotropy
magnetic properties
Magnets
nanomagnetism
Nickel
single-molecule magnets
trigonal pyramidal geometry
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Summary:A family of distorted trigonal pyramidal transition‐metal complexes [MII(N3N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single‐molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibiting pronounced SMM behavior. A family of distorted trigonal pyramidal transition‐metal complexes [MII(N3N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as potential candidates for mononuclear single‐molecule magnets (see figure).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201605528